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Conductivity increase due to nonequilibrium conditions in an actual quasi-one-dimensional conductor with charge- or spin-density-wave gap

E. M. Conwell and N. C. Banik

  • Webster Research Center, Webster, New York 14580

Phys. Rev. B 26, 530 – Published 15 July, 1982

DOI: https://doi.org/10.1103/PhysRevB.26.530

Abstract

We derive the gap equation for a uniform quasi-one-dimensional (1D) conductor with arbitrary band filling and use it to calculate the decrease in the gap of bis tetramethyl-tetraselenafulvalene hexafluorophosphate [(TMTSF)2PF6] due to the presence of excess electron-hole pairs. An actual 1D conductor with a charge- or spin-density-wave gap should be nonuniform due to the presence of various types of defects. For a nonuniform conductor we predict a new effect in high electric fields: gap decrease due to injection across internal barriers between regions of different gap. This is expected to give rise to a characteristic instability. It could explain the very large increases in conductivity with field observed in materials such as tetrathiafulvalene tetracyanoquinodimethane (TTF-TCNQ) and (TMTSF)2PF6.

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