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Long-wavelength excitations in incommensurate intergrowth compounds with application to Hg3δAsF6

J. D. Axe

Per Bak

  • Institute for Theoretical Physics, University of California, Santa Barbara, California 93106 and Department of Physics, Brookhaven National Laboratory, Upton, New York 11973

  • Institute for Theoretical Physics, University of California, Santa Barbara, California 93106 and University of Copenhagen, Universitetsparken 5, Copenhagen, Denmark

Phys. Rev. B 26, 4963 – Published 1 November, 1982

DOI: https://doi.org/10.1103/PhysRevB.26.4963

Abstract

There exists a variety of compounds consisting of two (or more) interpenetrating incommensurate lattices, e.g., Hg3δAsF6, tetrathiafulvalene iodide (TTF-Ix), Nowotny phases. In such materials one expects new hydrodynamic modes associated with a broken translational symmetry. We examine a continuum model of these excitations which appear as "extra" acoustic modes. We consider the case of Hg3δAsF6 explicitly and find a set of "generalized" elastic constants which violate conventional rotational symmetry relations in agreement with existing experiments. At high temperatures there are five acoustic modes; at low temperatures there are four in this material. Owing to the liquidlike properties of this material certain modes become purely dissipative in some propagation directions.

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