• Accepted Paper

Photodetachment energy of negative hydrogen ions

Maen Salman and Jean-Philippe Karr

Phys. Rev. A - Accepted 10 September, 2026

DOI: https://doi.org/10.1103/wq6v-v9bb

Abstract

We report a high-precision calculation of the photodetachment energy of the hydrogen anion H, also known as the electron affinity of the hydrogen atom. The nonrelativistic bound-state energy is obtained using an exact three-body approach, and supplemented by leading relativistic, quantum-electrodynamic, finite-nuclear-size, and hyperfine corrections. Our result is 6083.06447(68)cm1 for the detachment to the hydrogen ground-state hyperfine level (F=0), which is 220 times more precise than the best experimental determination to date, 6082.99(15)cm1, as reported by Lykke Beyond their intrinsic interest, these results provide critical input for antihydrogen physics, where controlled photodetachment of H+ offers a path to producing ultracold antihydrogen (and its isotopes) for precision experiments. We further determine the photodetachment thresholds for 2H and 3H into the ground hyperfine states of the corresponding hydrogenic atoms, yielding 6086.70679(68)cm1 for 2H(F=1/2) and 6087.87924(68)cm1 for 3H(F=0).

Export citation

Export citation

Choose format for download:

Download Citation

If the author has provided any supplemental materials with this article they will be available upon publication of the version of record.

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation