Double microwave shielding employs ${\sigma }^{+}$- and $\pi$-polarized microwave fields, tuned close to the lowest rotational transition, to engineer a long-range repulsive barrier between polar molecules. By preventing molecules from reaching the short range, this technique suppresses detrimental two-body losses and recently enabled the realization of molecular Bose-Einstein condensates and self-bound droplets. Yet, the optimal operating regimes of the shielding mechanism remain largely unexplored. Here, by leveraging the underlying universality of the scattering problem, we systematically map the four-dimensional microwave parameter space—spanned by the detunings and intensities of the two fields—to identify configurations that maximize both shielding efficiency and interaction tunability. We define optimal operating regimes as configurations that are strictly free of field-linked bound states while sufficiently suppressing two-body losses to exceed typical lifetimes of ultracold samples. In these regimes, we evaluate the elastic-to-inelastic collision ratios required for efficient evaporative cooling and explore the accessible tuning range of the effective dipolar interactions. Finally, to identify the best platforms for future quantum simulation experiments, we conduct a global survey of candidate molecular species under realistic field constraints. We identify heavy, strongly dipolar molecules as the most promising candidates, demonstrating that they can achieve extreme loss suppression—reaching two-body loss rates as low as ${10}^{-18}{\mathrm{cm}}^3/\mathrm{s}$—alongside robust interaction tunability using only moderate field strengths.

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• Atomic & molecular collisions
• Atomic & molecular processes in external fields
• Bose-Einstein condensates
• Cold and ultracold molecules
• Cooling & trapping
• Ultracold collisions