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The Paschen-Back Effect. VII. Configuration Interaction

J. B. Green

  • Mendenhall Laboratory of Physics, Ohio State University, Columbus, Ohio

Phys. Rev. 59, 69 – Published 1 January, 1941

DOI: https://doi.org/10.1103/PhysRev.59.69

Abstract

The spectrum of krypton furnishes a very fine example of the effect of configuration interaction. The levels 3s5 and 4d2, belonging to configurations of the same parity are less than 1 cm1 apart, and the Zeeman patterns of lines arising from them show large perturbations, both as regards positions and relative intensities of the components. A semiempirical theory is discussed which leads to excellent agreement with experiment.

See Also

The Paschen-Back Effect. I. LS Coupling; the P3D3 Multiplets of Zn and Cd

J. B. Green and D. E. Gray
Phys. Rev. 45, 273 (1934)

References (3)

  1. J. B. Green and J. F. Eichelberger, Phys. Rev. 56, 51 (1939)
  2. Roberson and Mack, Phys. Rev. 57, 1074 (1940) Mack and Laporte, 51, 291 (1937)
  3. E. U. Condon and G. H. Shortley, Theory of Atomic Spectra (Cambridge, 1935), 93(11)

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