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The Paschen-Back Effect. I. LS Coupling; the P3D3 Multiplets of Zn and Cd

J. B. Green and D. E. Gray

  • Mendenhall Laboratory of Physics, Ohio State University

Phys. Rev. 45, 273 – Published 15 February, 1934

DOI: https://doi.org/10.1103/PhysRev.45.273

Abstract

Darwin's calculations for Zeeman effect are applied to the Zn and Cd P3D3 multiplets. The frequencies and intensities thus calculated show very good agreement with the experimental values. A considerably smaller discrepancy between experiment and older quantum theory is noted for the Cd than for the Zn as should be expected because of the much larger multiplet separation in the case of the former.

See Also

The Paschen-Back Effect. II. JJ-Coupling (approx.)

J. B. Green and R. A. Loring
Phys. Rev. 46, 888 (1934)

The Paschen-Back Effect. IV. Mutual Spin-Orbit Interaction in Two-Electron Spectra

J. B. Green and R. A. Loring
Phys. Rev. 49, 632 (1936)

The Paschen-Back Effect. III. S22P Multiplets in Strong Fields

J. B. Green and R. A. Loring
Phys. Rev. 49, 630 (1936)

The Paschen-Back Effect. V. Theory of the Effect for Intermediate Coupling

J. B. Green and J. F. Eichelberger
Phys. Rev. 56, 51 (1939)

The Paschen-Back Effect. VI. The Spectrum of Neon

J. B. Green and J. A. Peoples, Jr.
Phys. Rev. 56, 54 (1939)

The Paschen-Back Effect. VII. Configuration Interaction

J. B. Green
Phys. Rev. 59, 69 (1941)

The Paschen-Back Effect. VIII. The Reality of the Distant Components

J. B. Green
Phys. Rev. 60, 343 (1941)

References (7)

  1. Heisenberg and Jordan, Zeits. f. Physik 37, 263 (1926)
  2. Darwin, Proc. Roy. Soc. A115, 1 (1927) K. Darwin, A118, 264 (1928)
  3. Kronig, Zeits. f. Physik 31, 885 (1925)
  4. Fowler, Phil. Mag. 1, 1079 (1925)
  5. Mensing, Zeits. f. Physik 39, 24 (1926)
  6. Green, Phys. Rev. 36, 157 (1930)
  7. Green and Loring in Phys. Rev. 43, 459 (1933)

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