Diffusion of Antimony in Silver

E. Sonder; L. Slifkin; C. T. Tomizuka

doi:10.1103/PhysRev.93.970

Access by Xinjiang University

Diffusion of Antimony in Silver

E. Sonder, L. Slifkin, and C. T. Tomizuka

Department of Physics, University of Illinois. Urbana, Illinois

PDF

Phys. Rev. 93, 970 – Published 1 March, 1954

DOI: https://doi.org/10.1103/PhysRev.93.970

Abstract

The diffusion coefficient of antimony tracers in single crystals of pure silver has been measured as a function of temperature over the range 468-942°C. The relation $D = D_{0} \exp (- \frac{H}{RT})$ was found to be obeyed with $H = 38 320$ cal/mole and $D_{0} = 0.169$ ${cm}^{2}$ /sec. These values are in marked disagreement with those appearing in the literature. The data suggest, in addition, that any variation with temperature in $D_{0}$ of the form $D_{0} = {D_{0}}^{'} T^{n}$ is such that $n$ probably lies in the range 0 to +½. This implies that any temperature variation of $H$ is probably less than 1 cal/mole deg.

References (12)

A. D. LeClaire, in Progress in Metal Physics, edited by B. Chalmers (Butterworth Scientific Publications, London, 1949 and 1953), Vols. I and IV F. Seitz, in Phase Transformations in Solids, edited by J. Smoluchowski (John Wiley and Sons, Inc., New York, 1951)
Slifkin, Lazarus, and Tomizuka, J. Appl. Phys. 23, 1405 (1952)
Omitted endnote
H. Francis and W. Colner, J. Electrochem. Soc. 97, 237 (1950)
G. Kehl, Principles of Metallographic Laboratory Practice (McGraw-Hill Book Company, Inc., New York, 1949)
Slifkin, Lazarus, and Tomizuka, J. Appl. Phys. 23, 1032 (1952)
W. Seith and E. Peretti, Z. Elektrochem. 42, 570 (1936)
A. S. Nowick, J. Appl. Phys. 22, 1182 (1951)
C. T. Tomizuka, Bull. Am. Phys. Soc. 28, No. 6, 18 (1953) C. T. Tomizuka and L. Slifkin (to be published)
C. Wagner, Z. physik. Chem. B38, 325 (1938) R. P. Johnson, Phys. Rev. 56, 814 (1939)
D. Lazarus, following paper [Phys. Rev. 93, 973 (1954)]
C. Zener in Imperfections in Nearly Perfect Crystals, edited by W. Shockley (John Wiley and Sons, Inc., New York, 1952)

[c1] A. D. LeClaire, in Progress in Metal Physics, edited by B. Chalmers (Butterworth Scientific Publications, London, 1949 and 1953), Vols. I and IV F. Seitz, in Phase Transformations in Solids, edited by J. Smoluchowski (John Wiley and Sons, Inc., New York, 1951)

[c2] Slifkin, Lazarus, and Tomizuka, J. Appl. Phys. 23, 1405 (1952)

[c3] Omitted endnote

[c4] H. Francis and W. Colner, J. Electrochem. Soc. 97, 237 (1950)

[c5] G. Kehl, Principles of Metallographic Laboratory Practice (McGraw-Hill Book Company, Inc., New York, 1949)

[c6] Slifkin, Lazarus, and Tomizuka, J. Appl. Phys. 23, 1032 (1952)

[c7] W. Seith and E. Peretti, Z. Elektrochem. 42, 570 (1936)

[c8] A. S. Nowick, J. Appl. Phys. 22, 1182 (1951)

[c9] C. T. Tomizuka, Bull. Am. Phys. Soc. 28, No. 6, 18 (1953) C. T. Tomizuka and L. Slifkin (to be published)

[c10] C. Wagner, Z. physik. Chem. B38, 325 (1938) R. P. Johnson, Phys. Rev. 56, 814 (1939)

[c11] D. Lazarus, following paper [Phys. Rev. 93, 973 (1954)]

[c12] C. Zener in Imperfections in Nearly Perfect Crystals, edited by W. Shockley (John Wiley and Sons, Inc., New York, 1952)

Physical Review Journals Archive

Export citation

Export citation

Diffusion of Antimony in Silver

Abstract

References (12)

Outline

Information

Filter

Filter

Article Lookup

Enter a citation