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Drift Velocity of Ions in Oxygen, Nitrogen, and Carbon Monoxide
Phys. Rev. 89, 708 – Published 15 February, 1953
DOI: https://doi.org/10.1103/PhysRev.89.708
Abstract
The drift velocities of ions of the parent gas in oxygen, nitrogen, and carbon monoxide have been measured as a function of field strength to pressure ratio by techniques previously reported. Oxygen gave results similar to those in the rare gases reported previously. A log-log plot of drift velocity against in volts/(cm×mm Hg) starts with a slope near unity which gradually decreases to one-half at high values of . The mobility, extrapolated to zero field and atmospheric pressure is 2.25 /volt-sec. Nitrogen and carbon monoxide both show a novel characteristic; the drift velocity first rises with but reaches a maximum and actually decreases, then finally resumes a more normal rise with as described for oxygen. It is believed that at high the drift velocity is characteristic of ions and C ions, respectively. At low fields the ion in nitrogen is believed to be . In CO the ion at low fields is believed to be C, with (C being formed at intermediate fields. The results are complicated by an additional ion which appears in the range of from 95 to 250 and which has a higher speed than the other ion. It is suspected of being .
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