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  • Access by Xinjiang University

Drift Velocity of Ions in Oxygen, Nitrogen, and Carbon Monoxide

Robert N. Varney*

  • Bell Telephone Laboratories, Murray Hill, New Jersey

  • *Now at Washington University, St. Louis, Missouri.

Phys. Rev. 89, 708 – Published 15 February, 1953

DOI: https://doi.org/10.1103/PhysRev.89.708

Abstract

The drift velocities of ions of the parent gas in oxygen, nitrogen, and carbon monoxide have been measured as a function of field strength to pressure ratio by techniques previously reported. Oxygen gave results similar to those in the rare gases reported previously. A log-log plot of drift velocity against Ep0 in volts/(cm×mm Hg) starts with a slope near unity which gradually decreases to one-half at high values of Ep0. The mobility, extrapolated to zero field and atmospheric pressure is 2.25 cm2/volt-sec. Nitrogen and carbon monoxide both show a novel characteristic; the drift velocity first rises with Ep0 but reaches a maximum and actually decreases, then finally resumes a more normal rise with Ep0 as described for oxygen. It is believed that at high Ep0 the drift velocity is characteristic of N2+ ions and CO+ ions, respectively. At low fields the ion in nitrogen is believed to be N4+. In CO the ion at low fields is believed to be CO+, with (CO)2+ being formed at intermediate fields. The results are complicated by an additional ion which appears in the range of Ep0 from 95 to 250 and which has a higher speed than the other ion. It is suspected of being C+.

References (8)

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