Theory of Magnetic Resonance in Nitric Oxide

Henry Margenau; Allan Henry

doi:10.1103/PhysRev.78.587

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Theory of Magnetic Resonance in Nitric Oxide

Henry Margenau and Allan Henry

Sloane Physics Laboratory, Yale University, New Haven Connecticut

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Phys. Rev. 78, 587 – Published 1 June, 1950

DOI: https://doi.org/10.1103/PhysRev.78.587

Abstract

The paper presents a theoretical study of the effect of a magnetic field on the lowest of the ${}^{2}Π_{\frac{3}{2}}$ levels of $N^{14}$ $O^{16}$ . The molecular Zeeman effect is calculated in detail and found to yield good agreement with experiment. Consideration is given to the energy of interaction, (a), of the spin of the $N^{14}$ nucleus with the total electronic angular momentum in the external field, and (b) of the quadrupole moment of $N^{14}$ with the electric field at the $N^{14}$ nucleus. The last section contains an evaluation of the matrix elements needed in the computation of absolute intensities for the transitions within the ${}^{2}Π_{\frac{3}{2}}$ level.

References (11)

R. Beringer and J. G. Castle, Jr., Phys. Rev. 78, 581 (1950)
G. Herzberg, Molecular Spectra and Molecular Structure I (Prentice-Hall, Inc., New York, 1939)
W. Jevons, Band Spectra of Diatomic Molecules (Cambridge University Press, London, 1932), p. 252
G. C. Wick, Zeits. f. Physik 85, 25 (1933)
E. L. Hill and J. H. Van Vleck, Phys. Rev. 32, 250 (1928) E. L. Hill, 34, 1507 (1929)
R. S. Mulliken and A. Christie, Phys. Rev. 38, 87 (1931)
E. L. Hill, Phys. Rev. 34, 1507 (1929)
R. H. Gillette and E. H. Eyster, Phys. Rev. 56, 1113 (1939)
H. B. G. Casimir, On the Interaction between Atomic Nuclei and Electrons (Haarlem, DeErven F. Bohn N.V. 1936) J. M. Jauch, Phys. Rev. 72, 716 (1947) A. Nordsieck, 58, 310 (1940)
E. U. Condon and G. H. Shortley, Theory of Atomic Spectra (Cambridge University Press, London, 1935), p. 59 ff
Reiche and Rademacher, Zeits. f. Physik 41, 453 (1927)

[c1] R. Beringer and J. G. Castle, Jr., Phys. Rev. 78, 581 (1950)

[c2] G. Herzberg, Molecular Spectra and Molecular Structure I (Prentice-Hall, Inc., New York, 1939)

[c3] W. Jevons, Band Spectra of Diatomic Molecules (Cambridge University Press, London, 1932), p. 252

[c4] G. C. Wick, Zeits. f. Physik 85, 25 (1933)

[c5] E. L. Hill and J. H. Van Vleck, Phys. Rev. 32, 250 (1928) E. L. Hill, 34, 1507 (1929)

[c6] R. S. Mulliken and A. Christie, Phys. Rev. 38, 87 (1931)

[c7] E. L. Hill, Phys. Rev. 34, 1507 (1929)

[c8] R. H. Gillette and E. H. Eyster, Phys. Rev. 56, 1113 (1939)

[c9] H. B. G. Casimir, On the Interaction between Atomic Nuclei and Electrons (Haarlem, DeErven F. Bohn N.V. 1936) J. M. Jauch, Phys. Rev. 72, 716 (1947) A. Nordsieck, 58, 310 (1940)

[c10] E. U. Condon and G. H. Shortley, Theory of Atomic Spectra (Cambridge University Press, London, 1935), p. 59 ff

[c11] Reiche and Rademacher, Zeits. f. Physik 41, 453 (1927)

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Theory of Magnetic Resonance in Nitric Oxide

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