All JournalsPhysics Magazine

Export citation

Export citation

Choose format for download:

Download Citation
  • Access by Xinjiang University

A Note on the Centrifugal Stretching in Axially Symmetric Molecules

Harald H. Nielsen

  • Mendenhall Laboratory of Physics, Ohio State University, Columbus, Ohio

Phys. Rev. 78, 415 – Published 15 May, 1950

DOI: https://doi.org/10.1103/PhysRev.78.415

Abstract

It is demonstrated that the degenerate Coriolis splitting of a rotational level, K0, of a molecule which is in an excited perpendicular vibration state is influenced by centrifugal distortion. The effect is of the form aK3+bJ(J+1)K. The effect of this distortion on the infra-red spectrum is of the same order of magnitude as the ordinary centrifugal distortion. It is further shown that by redefining the Coriolis coupling coefficient ζt the rotational energy of a symmetric molecule may be written in the form (Ehc)=[J(J+1)K2]Bv+L2Cv[J(J+1)K2]2DJ[J(J+1)K2]L2DJLL4DL where L=KΣtltζt(z).

References (7)

  1. Z. I. Slawsky and D. M. Dennison, J. Chem. Phys. 7, 509 (1939)
  2. H. H. Nielsen, Phys. Rev. 60, 794 (1941)
  3. D. M. Dennison, Phys. Rev. 41, 304 (1932)
  4. W. H. Shaffer, Rev. Mod. Phys. 16, 245 (1944)
  5. H. H. Nielsen, Phys. Rev. 77, 130 (1950)
  6. H. H. Nielsen, Phys. Rev. 70, 184 (1946)
  7. A. Sayvetz, J. Chem. Phys. 7, 282 (1939)

Outline

Information

Sign In to Your Journals Account

Filter

Filter

Article Lookup

Enter a citation