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A Note on the Centrifugal Stretching in Axially Symmetric Molecules
Phys. Rev. 78, 415 – Published 15 May, 1950
DOI: https://doi.org/10.1103/PhysRev.78.415
Abstract
It is demonstrated that the degenerate Coriolis splitting of a rotational level, , of a molecule which is in an excited perpendicular vibration state is influenced by centrifugal distortion. The effect is of the form . The effect of this distortion on the infra-red spectrum is of the same order of magnitude as the ordinary centrifugal distortion. It is further shown that by redefining the Coriolis coupling coefficient the rotational energy of a symmetric molecule may be written in the form where .
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