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  • Access by Xinjiang University

Nuclear Spins of the Carbon Isotopes

F. A. Jenkins

  • Department of Physics, University of California, Berkeley, California

Phys. Rev. 74, 355 – Published 15 August, 1948

DOI: https://doi.org/10.1103/PhysRev.74.355

Abstract

High dispersion spectrograms of the Swan bands of diatomic carbon are obtained from samples enriched to 50 percent and 40 percent, respectively, in C13 and C14. The method of exciting an intense spectrum with microgram samples is described. To permit measurements of the alternating-intensity ratio, current densities in the source had to be limited so that the Λ-type doublets were well resolved. For C13, photometric measurements of this ratio give 3:1, showing that the nuclear spin I=12. The antisymmetric rotational levels have the higher statistical weight (Fermi-Dirac statistics). For C14, only the lines from symmetric levels appear. This shows clearly that I=0 for C14, and that the nucleus obeys Einstein-Bose statistics. Wave numbers are given of lines in the R branches of the 0,0 band in the range K=12 to 20, due to all molecular species containing C12, C13 and C14. An isotope effect in the splittings of the electronic triplets is investigated, and found to agree with that calculated from the general term formula for Π3 states.

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