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Nuclear Spins of the Carbon Isotopes
Phys. Rev. 74, 355 – Published 15 August, 1948
DOI: https://doi.org/10.1103/PhysRev.74.355
Abstract
High dispersion spectrograms of the Swan bands of diatomic carbon are obtained from samples enriched to 50 percent and 40 percent, respectively, in and . The method of exciting an intense spectrum with microgram samples is described. To permit measurements of the alternating-intensity ratio, current densities in the source had to be limited so that the -type doublets were well resolved. For , photometric measurements of this ratio give 3:1, showing that the nuclear spin . The antisymmetric rotational levels have the higher statistical weight (Fermi-Dirac statistics). For , only the lines from symmetric levels appear. This shows clearly that for , and that the nucleus obeys Einstein-Bose statistics. Wave numbers are given of lines in the branches of the 0,0 band in the range , due to all molecular species containing , and . An isotope effect in the splittings of the electronic triplets is investigated, and found to agree with that calculated from the general term formula for states.
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