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The Self-Diffusion Coefficient of Uranium Hexafluoride

Edward P. Ney and Fontaine C. Armistead*

  • Rouss Physical Laboratory, University of Virginia, Charlottesville, Virginia

  • *Now at Clinton Laboratories, Oak Ridge, Tennessee.

Phys. Rev. 71, 14 – Published 1 January, 1947

DOI: https://doi.org/10.1103/PhysRev.71.14

Abstract

A method is reported for measuring the self-diffusion coefficient of a vapor by observing with a mass spectrometer the rate at which material enriched in one isotope diffuses into normal material in an apparatus of known geometry. A value of ρD (where ρ is the density and D the diffusion constant) was obtained for uranium hexafluoride at 30°C. Knowledge of the viscosity together with the constants reported here allow calculation of the molecular force law.

References (4)

  1. Omitted endnote

  2. A. O. Nier, E. P. Ney, and M. G. Inghram, "Null method for the comparison of two ion currents in a mass spectrometer," Chicago Meeting of the American Physical Society, June 22, 1946
  3. Maxwell, Electricity and Magnetism (Oxford, 1892), p. 434 Lord Rayleigh, Theory of Sound (The MacMillan Company, 1878), Vol. II, pp. 291-295
  4. Loeb, Kinetic Theory of Gases (McGraw-Hill Book Company, Inc., New York, 1934), pp. 268-272

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