The Effect of Pressure upon the Dielectric Constants of Liquids

Benton Brooks Owen; Stuart R. Brinkley, Jr

doi:10.1103/PhysRev.64.32

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The Effect of Pressure upon the Dielectric Constants of Liquids

Benton Brooks Owen

Stuart R. Brinkley, Jr.^*,†

Sterling Chemistry Laboratory, Yale University, New Haven, Connecticut

Mallinckrodt Chemical Laboratory, Harvard University, Cambridge, Massachusetts

^*National Research Fellow in Chemistry.
^†Present address, Department of Chemistry, Cornell University, Ithaca, New York.

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Phys. Rev. 64, 32 – Published 1 July, 1943

DOI: https://doi.org/10.1103/PhysRev.64.32

Abstract

An empirical equation containing two parameters $A$ and $B$ is shown to express the isothermal variation of the dielectric constants of liquids with pressure. The equation is analogous to the Tait equation for the variation of the densities of liquids with pressure. The parameter $B$ is common to both equations, and therefore may be determined independently from either dielectric constants or densities. Furthermore $B$ can be eliminated between the two equations to give a linear relationship between the reciprocals of the dielectric constant and the density. It is shown that this linear relationship may be derived from Tammann's hypothesis and electrostatic theory.

References (17)

F. T. Gucker, Jr., Chem. Rev. 13, 111 (1933)
Omitted endnote
P. G. Tait, "Report on some of the physical properties of fresh water and sea water," Physics and Chemistry of the Voyage of H.M.S. Challenger, Vol. II, Part IV, S.P., LXI (1888)
R. E. Gibson, J. Am. Chem. Soc. 56, 4 (1934) ibid., 57, 284 (1935) A. Wohl, Zeits. f. physik. Chemie 99, 234 (1921) H. Carl, ibid. 101, 238 (1922)
S. Kyropoulos, Zeits. f. Physik 40, 507 (1926)
W. E. Danforth, Jr., Phys. Rev. 38, 1224 (1931)
C. Francke, Ann. d. Physik 77, 159 (1925)
Omitted endnote
Omitted endnote
Omitted endnote
Omitted endnote
Omitted endnote
R. E. Gibson and J. F. Kincaid, J. Am. Chem. Soc. 60, 511 (1938)
G. Tammann, Über die Beziehungen zwischen den innern Kräften und Eigenschaften der Lösungen (Voss, Liepzig, 1907), p. 36
G. Scatchard, Chem. Rev. 3, 383 (1927) J. Chem. Phys. 9, 34 (1941)
M. Born, Zeits. f. Physik 1, 45 (1920) E. Guntelberg, Zeits. f. physik. Chemie 123, 199 (1926)
P. Debye and J. McAulay, Physik. Zeits. 26, 22 (1925) P. Debye, Zeits. f. physik. Chemie 130, 56 (1927) J. A. V. Butler, J. Phys. Chem. 33, 1015 (1929) H. S. Harned and N. N. T. Samaras, J. Am. Chem. Soc. 54, 9 (1932)

[c1] F. T. Gucker, Jr., Chem. Rev. 13, 111 (1933)

[c2] Omitted endnote

[c3] P. G. Tait, "Report on some of the physical properties of fresh water and sea water," Physics and Chemistry of the Voyage of H.M.S. Challenger, Vol. II, Part IV, S.P., LXI (1888)

[c4] R. E. Gibson, J. Am. Chem. Soc. 56, 4 (1934) ibid., 57, 284 (1935) A. Wohl, Zeits. f. physik. Chemie 99, 234 (1921) H. Carl, ibid. 101, 238 (1922)

[c5] S. Kyropoulos, Zeits. f. Physik 40, 507 (1926)

[c6] W. E. Danforth, Jr., Phys. Rev. 38, 1224 (1931)

[c7] C. Francke, Ann. d. Physik 77, 159 (1925)

[c8] Omitted endnote

[c9] Omitted endnote

[c10] Omitted endnote

[c11] Omitted endnote

[c12] Omitted endnote

[c13] R. E. Gibson and J. F. Kincaid, J. Am. Chem. Soc. 60, 511 (1938)

[c14] G. Tammann, Über die Beziehungen zwischen den innern Kräften und Eigenschaften der Lösungen (Voss, Liepzig, 1907), p. 36

[c15] G. Scatchard, Chem. Rev. 3, 383 (1927) J. Chem. Phys. 9, 34 (1941)

[c16] M. Born, Zeits. f. Physik 1, 45 (1920) E. Guntelberg, Zeits. f. physik. Chemie 123, 199 (1926)

[c17] P. Debye and J. McAulay, Physik. Zeits. 26, 22 (1925) P. Debye, Zeits. f. physik. Chemie 130, 56 (1927) J. A. V. Butler, J. Phys. Chem. 33, 1015 (1929) H. S. Harned and N. N. T. Samaras, J. Am. Chem. Soc. 54, 9 (1932)

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The Effect of Pressure upon the Dielectric Constants of Liquids

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