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  • Access by Xinjiang University

Isotope Shifts in Some Lines of Nitrogen

John R. Holmes

  • Department of Physics, University of California, Berkeley, California

Phys. Rev. 63, 41 – Published 1 January, 1943

DOI: https://doi.org/10.1103/PhysRev.63.41

Abstract

The line spectrum of a mixture of approximately 70 atomic percent N15 to 30 atomic percent N14 was photographed with a Fabry-Perot interferometer. The source used was a liquid-air cooled quartz tube with external electrodes excited by a 12-meter oscillator. The tube was charged with helium at a few mm pressure containing about 0.03 mm of the before-mentioned nitrogen isotope mixture. The lines from this discharge were so sharp that it was possible to resolve the two components due to N14 and N15 in nine infra-red lines. No nitrogen lines were found in this type of discharge in the visible or ultraviolet. The oscillator excitation produced a remarkably high intensity in the lines observed. The lines arising from P4P4 and S4P4 transitions showed a negative isotope shift of the order of 0.06 cm1. Those from P2P2 transitions showed a positive shift of the order of 0.07 cm1. The variations in the isotope shifts within the P2P2 multiplets indicate some deviation from Russell-Saunders coupling. No hyperfine structure in either component was observed in any of the lines. The directions of the shifts were checked by obtaining the abundance ratio of the isotopes in the discharge from the intensities of the isotopic heads in the second positive N2 bands.

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