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  • Access by Xinjiang University

On the Polar Vibrations of Alkali Halides

R. H. Lyddane

R. G. Sachs* and E. Teller

  • University of North Carolina, Chapel Hill, North Carolina

  • George Washington University, Washington, D. C.

  • *Now at Purdue University, Lafayette Indiana.

Phys. Rev. 59, 673 – Published 15 April, 1941

DOI: https://doi.org/10.1103/PhysRev.59.673

Abstract

The long wave-length, polar lattice vibrations of alkali halide crystals are discussed without making any specific assumptions about the detailed interactions between the ions. This is made possible by the introduction of the effective charge, e*, of an ion defined as follows: All of the positive ions in a crystal slab are displaced by an equal amount in a direction perpendicular to the faces of the slab and all of the negative ions in the opposite direction. Then e* is the ratio of the dipole moment per ion pair induced in the slab by this displacement to the relative displacement of the positive and the negative ions. Expressions are obtained for the frequency, ωl, of the longitudinal vibration and the frequency, ωt, of the transverse vibration in terms of the dielectric constant, k, of the crystal, the dielectric constant, k0, obtained by extrapolating the square of the index of refraction of the crystal from high frequencies to zero frequency, and e*. The ratio of the two frequencies is found to be independent of e* and given by ωlωt=(kk0)12.

References (7)

  1. R. H. Lyddane and K. F. Herzfeld, Phys. Rev. 54, 846 (1938)
  2. H. Fröhlich and N. F. Mott, Proc. Roy. Soc. A171, 496 (1939)
  3. Omitted endnote

  4. Omitted endnote

  5. R. H. Lyddane, K. F. Herzfeld and R. G. Sachs, Phys. Rev. 58, 1008 (1940)
  6. M. Born, Preuss. Akad. Wiss. (Berlin) 29, 604 (1918) Physik. Zeits. 19, 539 (1918) M. Born and M. Goeppert-Mayer, Handbuch der Physik 24/2, p. 646
  7. K. L. Wolf and K. F. Herzfeld, Handbuch der Physik Vol. 20, p. 517

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