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Resonance Broadening of the Sodium Lines
Phys. Rev. 59, 151 – Published 15 January, 1941
DOI: https://doi.org/10.1103/PhysRev.59.151
Abstract
By direct measurement of the contours of the line wings, the resonance broadening of the sodium lines in absorption was determined for vapor pressures of sodium ranging from to 70 mm Hg with negligible amount of foreign gases. Over nearly the entire range, the half-intensity width varied linearly with the density of the absorbing atoms; i.e., —the constant being 1.6 times that predicted by theory but much less than the corresponding experimental results for potassium. Above 5 mm pressure, increased slightly faster than ; moreover, the contour for the absorption coefficient was more adequately represented by an inverse cube contour than by the inverse square. Somewhat in contradiction to theory, the relative width, was 1.12. No definite evidence of van der Waals force was observed at the higher pressures; likewise no appreciable shifts or asymmetries. The natural width measured was consistent with previous results.
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