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Note on Pressure Effects in Band Spectra

Henry Margenau

  • Yale University

Phys. Rev. 49, 596 – Published 15 April, 1936

DOI: https://doi.org/10.1103/PhysRev.49.596

Abstract

A simple theory is presented describing pressure effects on band lines, insofar as they are due to foreign perturbing molecules without permanent polarity. Results are: Band lines are shifted and broadened much in the manner of atomic lines as a result of van der Waals interactions. Calculations with the models of a rigid rotator and a simple harmonic oscillator, for which formulas are given, show that the effects are practically independent of rotational and vibrational quantum numbers.

References (1)

  1. W. W. Watson and G. F. Hull, Jr., Phys. Rev.

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