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Band Spectra of BiBr, BiCl, BiF, and BiI in Absorption
Phys. Rev. 49, 41 – Published 1 January, 1936
DOI: https://doi.org/10.1103/PhysRev.49.41
Abstract
The band spectra of BiBr, BiCl, BiF, and BiI have been examined in absorption and a vibrational analysis made for each of the observed systems. For BiBr there are two systems for each of the isotopes and with origins at 4045.7A and 4869.1A. The lower frequency system degrades to the red, but the direction in which the other degrades is in doubt. In BiCl a band system lying between and 4000A has been found for each of the isotopes and in addition to the system at -5500A reported by Saper. The vibrational analyses are confirmed by the respective isotope shifts. One band system between and 4900A for BiF and one between and 4300A for BiI have been observed and analyzed.
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