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The Infrared Absorption Spectrum of Silane

Wendell B. Steward and Harald H. Nielsen

  • Mendenhall Laboratory of Physics, Ohio State University

Phys. Rev. 47, 828 – Published 1 June, 1935

DOI: https://doi.org/10.1103/PhysRev.47.828

Abstract

The spectrum of silane has been investigated to beyond 13.0μ. Bands, enumerated in the order of their intensities, were located at 11.0μ (910 cm1), 4.6μ (2183 cm1), 3.17μ (3153 cm1), 3.23μ (3095 cm1), 5.5μ (1820 cm1) and 2.3μ (4360 cm1). Four of these regions have been investigated under higher dispersion and partially resolved. The spectrum appears quite similar, except for certain details, to that of methane and by analogy the above bands have been identified as ν4, ν3, ν1+ν4, ν3+ν4, 2ν4 and 2ν3. From these values one may determine ν1 which takes the value 2243 cm1. By the methods developed by Dennison and Johnston one may determine the moment of inertia which from the most probable value for the spacing between lines takes the value I0=8.9×1040 g cm2.

References (4)

  1. W. W. Coblentz, Publ. of Carnegie Inst., Washington, D. C. (1905) J. P. Cooley, Astrophys J. 62, 73 (1925) J. Ellis, Proc. Nat. Acad. Sci. 13, 202 (1927) A. Adel and V. M. Slipher, Phys. Rev. 46, 902 (1934)
  2. Teller and Tisza, Zeits. f. Physik 73, 791 (1932)
  3. D. M. Dennison and M. Johnston, Phys. Rev. 47, 93 (1935)
  4. W. Steward and H. H. Nielsen, J. Chem. Phys. 2, 712 (1934)

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