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Transformations in the Theory of Complex Spectra
Phys. Rev. 43, 451 – Published 15 March, 1933
DOI: https://doi.org/10.1103/PhysRev.43.451
Abstract
Four transformations are considered in detail: that from the zero-order scheme to the -coupling scheme, that from the zero-order scheme to the -coupling scheme, that connecting these two zero-order schemes, and that connecting the - and the -coupling schemes. A correlation between the states of the configuration with electrons in shell plus other electrons and those of the configuration with electrons missing from shell plus the same other electrons is found such that all of these transformations are the same for the two configurations. The transformation between zero-order states in two different schemes is considered in general and a general expression (3.10) is found giving this transformation for an almost closed shell in terms of the transformation for the corresponding simple configuration. Finally, a direct method is found for obtaining the transformation from -coupling to -coupling for any two-electron configuration, and this transformation is given explicitly for all such configurations up to . This then furnishes the -coupling transformation also for , , , , , , , and , the configurations for which the -coupling scheme is most useful.
References (12)
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- Johnson, [8] Inglis and Ginsburg, Phys. Rev. 43, 194 (1933)