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Transformations in the Theory of Complex Spectra

George H. Shortley

  • Palmer Physical Laboratory, Princeton University

Phys. Rev. 43, 451 – Published 15 March, 1933

DOI: https://doi.org/10.1103/PhysRev.43.451

Abstract

Four transformations are considered in detail: that from the zero-order nlmlms scheme to the LS-coupling scheme, that from the zero-order nljmj scheme to the jj-coupling scheme, that connecting these two zero-order schemes, and that connecting the LS- and the jj-coupling schemes. A correlation between the states of the configuration with ε electrons in shell S plus η other electrons and those of the configuration with ε electrons missing from shell S plus the same η other electrons is found such that all of these transformations are the same for the two configurations. The transformation between zero-order states in two different schemes is considered in general and a general expression (3.10) is found giving this transformation for an almost closed shell in terms of the transformation for the corresponding simple configuration. Finally, a direct method is found for obtaining the transformation from LS-coupling to jj-coupling for any two-electron configuration, and this transformation is given explicitly for all such configurations up to dd. This then furnishes the LSjj-coupling transformation also for p4, p5s, p5p, p5d, d8, d9s, d9p, and d9d, the configurations for which the jj-coupling scheme is most useful.

References (12)

  1. Ufford and Shortley, Phys. Rev. 42, 167 (1932), §2
  2. Shortley, Phys. Rev. 40, 185 (1932)
  3. §5 of [2]
  4. Omitted endnote

  5. Omitted endnote

  6. Omitted endnote

  7. Omitted endnote

  8. Güttinger and Pauli, Zeits. f Physik 67, 743 (1931) M. H. Johnson, Phys. Rev. 38, 1628 (1931)
  9. Part II of [2]
  10. Wigner, Gruppentheorie, p. 206
  11. Omitted endnote

  12. Johnson, [8] Inglis and Ginsburg, Phys. Rev. 43, 194 (1933)

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