Simultaneous Ionization and Dissociation of Oxygen and Intensities of the Ultra-violet <span class="aps-inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><mrow><msubsup><mrow><mi mathvariant="normal">O</mi></mrow><mrow><mn>2</mn></mrow><mrow><mo>+</mo></mrow></msubsup></mrow></math></span> Bands

E. C. G. Stueckelberg

doi:10.1103/PhysRev.34.65

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Simultaneous Ionization and Dissociation of Oxygen and Intensities of the Ultra-violet $O_{2}^{+}$ Bands

E. C. G. Stueckelberg

Palmer Physical Laboratory, Princeton University

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Phys. Rev. 34, 65 – Published 1 July, 1929

DOI: https://doi.org/10.1103/PhysRev.34.65

Abstract

Observations by Hogness and Lunn, Smyth and Stueckelberg, showing that $O^{+}$ is formed from the neutral molecule by a single impact of about 20 volts, are explained from the potential energy curves of the molecule and ion. These have been obtained from a method given by P. M. Morse, and from the empirical law ${r_{0}}^{3} ω_{0} = 3000 A$ ${cm}^{- 1}$ . The intensities of the ultra-violet $O_{2}^{+}$ bands have been calculated from the same curves and are in good agreement with experiment.

References (11)

Franck u. Jordan, Anregung v. Quantensprungen p. 273
Mackay, Phys. Rev. 24, 319 (1924)
Hogness and Lunn, Phys. Rev. 27, 732 (1926)
Smyth and Stueckelberg, Phys. Rev. 32, 779 (1928)
Birge, Molecular Spectra in Gases, p. 232
R. S. Mulliken, Phys. Rev. 32, 186 and 761 (1928)
P. M. Morse, Phys. Rev. 34, 57 (1929)
J. Franck, Trans. Far. Soc. 21, part 3 (1925)
E. U. Condon, Phys. Rev. 32, 858 (1928)
E. U. Condon, Phys. Rev. 28, 1182 (1926)
R. C. Johnson, Proc. Roy. Soc. 105A, 683 (1924)

[c1] Franck u. Jordan, Anregung v. Quantensprungen p. 273

[c2] Mackay, Phys. Rev. 24, 319 (1924)

[c3] Hogness and Lunn, Phys. Rev. 27, 732 (1926)

[c4] Smyth and Stueckelberg, Phys. Rev. 32, 779 (1928)

[c5] Birge, Molecular Spectra in Gases, p. 232

[c6] R. S. Mulliken, Phys. Rev. 32, 186 and 761 (1928)

[c7] P. M. Morse, Phys. Rev. 34, 57 (1929)

[c8] J. Franck, Trans. Far. Soc. 21, part 3 (1925)

[c9] E. U. Condon, Phys. Rev. 32, 858 (1928)

[c10] E. U. Condon, Phys. Rev. 28, 1182 (1926)

[c11] R. C. Johnson, Proc. Roy. Soc. 105A, 683 (1924)

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Simultaneous Ionization and Dissociation of Oxygen and Intensities of the Ultra-violet $O_{2}^{+}$ Bands

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Simultaneous Ionization and Dissociation of Oxygen and Intensities of the Ultra-violet O2+ Bands

Abstract

References (11)

Simultaneous Ionization and Dissociation of Oxygen and Intensities of the Ultra-violet $O_{2}^{+}$ Bands