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Rotational Terms in the MgH Bands

William W. Watson and Philip Rudnick

  • The University of Chicago (W.W.W.) Washington, D. C. (P.R.)

Phys. Rev. 29, 413 – Published 1 March, 1927

DOI: https://doi.org/10.1103/PhysRev.29.413

Abstract

Rotational term data for the green MgH bands.—The values of the rotational terms for the vibrational states ½, 32, and 52 in the green MgH bands are tabulated.

Analytical representation of the terms. The Kratzer, Kramers and Pauli formula is applied to the data with the following values giving the best fit: jmin=12, jmin=12, σ=12, σ small (<½), ε and ε small (≅0). The term m=1 exists, thereby making it impossible to let j=m1. Other predicted electronic quantum numbers are shown to agree less well with the observed ΔF values.

References (10)

  1. Watson and Rudnick, Astrophys. J. 63, 20 (1926)
  2. Mulliken, Proc. Nat. Acad. Sci. 12, 144, 338 (1926) Phys. Rev. 28, 481, 1202 (1926)
  3. Mecke, Zeits. f. Physik 36, 802 (1926)
  4. Hund, Zeits. f. Physik 36, 657 (1926)
  5. Watson, Nature, 117, 692 (1926)
  6. Mulliken, Phys. Rev. 28, 1206 (1926)
  7. Omitted endnote

  8. Kratzer, Ann. d. Physik 71, 72 (1923)
  9. W. W. Watson, Phys. Rev. 27, 801 (1926)
  10. Kratzer (Zeits. f. Physik 23, 298 (1924)

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