Microwave Spectroscopy of O<span class="aps-inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><mrow><msup><mrow><mi mathvariant="normal">H</mi></mrow><mrow><mo>−</mo></mrow></msup></mrow></math></span> Ions in the KCl and NaCl Lattices

R. S. Scott; W. H. Flygare

doi:10.1103/PhysRev.182.445

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Microwave Spectroscopy of O $H^{-}$ Ions in the KCl and NaCl Lattices

R. S. Scott and W. H. Flygare

Materials Research Laboratory and Noyes Chemical Laboratory, University of Illinois, Urbana, Illinois 61801

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Phys. Rev. 182, 445 – Published 10 June, 1969

DOI: https://doi.org/10.1103/PhysRev.182.445

Abstract

Microwave resonant absorption has been observed in O $H^{-}$ -doped KCl and NaCl crystals. Several lines were observed from 8-40 GHz by using relatively standard microwave spectroscopic techniques. The zero-field spectra obtained here indicate that the O $H^{-}$ ion experiences a strong $C_{4 v}$ potential in addition to the expected octahedral crystal field. The $C_{4 v}$ potential probably arises from a shift of the O $H^{-}$ center of mass from the lattice site.

References (29)

U. Kuhn and F. Luty, Solid State Commun. 2, 281 (1964) ibid.3, 31 (1965) ibid.4, 31 (1956)
I. Shepherd and G. Feher, Phys. Rev. Letters 15, 149 (1965)
U. Bosshard, R. W. Dreyfus, and W. Känzig, Phys. Kondensierten Materie 4, 254 (1965)
H. B. Shore, Phys. Rev. 151, 570 (1966)
A. F. Devonshire, Proc. Roy. Soc. (London) A153, 601 (1936)
V. Narayanamurti, Phys. Rev. Letters 13, 693 (1964)
G. Feher, I. Shepherd, and H. B. Shore, Phys. Rev. Letters 16, 500 (1966)
L. D. Shearer and T. L. Estle, Compt Rend. 14, 644 (1966) Solid State Commun. 4, 639 (1966)
W. E. Bron and R. W. Dreyfus, Phys. Rev. Letters 16, 165 (1966) Phys. Rev. 163, 304 (1967)
M. E. Baur and W. R. Salzman, Phys. Rev. 151, 710 (1966)
W. N. Lawless, Phys. Kondensierten Materie 5, 100 (1966)
C. K. Chau, M. V. Klein, and B. Wedding, Phys. Rev. Letters 17, 521 (1966)
B. Wedding, thesis, University of Illinois, 1968, (unpublished) B. Wedding and M. V. Klein, Phys. Rev. 177, 1274 (1969)
M. V. Klein, B. Wedding, and M. A. Levine, Phys. Rev. 180, 902 (1969)
M. V. Klein, Phys. Rev. 141, 489 (1966)
W. H. Flygare, W. Hüttner, R. L. Shoemaker, and P. D. Foster, J. Chem. Phys. 50, 1714 (1969)
M. V. Klein, S. O. Kennedy, T. I. Gie, and B. Wedding, Mater. Res. Bull. 3, 677 (1968)
W. H. Flygare, J. Chem. Phys. 39, 2263 (1963)
[18]
D. R. Bosomworth, Solid State Commun. 5, 681 (1967)
M. E. Baur and W. R. Salzman, Phys. Rev. Letters 18, 590 (1967)
H. S. Sack and M. C. Moriarity, Solid State Commun. 3, 93 (1965)
G. Lombardo and R. O. Pohl, Phys. Rev. Letters 15, 291 (1965)
D. Hocherl, D. Blumenstock, and H. C. Wolf, Phys. Letters 24A, 511 (1967)
G. Hocherl and H. C. Wolf, Phys. Letters 27A, 133 (1968)
M. T. Bowers, G. I. Kerley, and W. H. Flygare, J. Chem. Phys. 45, 3399 (1966)
F. Luty, J. Phys. (Paris) 28, Suppl. C-4, 120 (1967)
R. S. Scott, thesis, University of Illinois, 1968 (unpublished)
R. D. Kirby, A. E. Hughes, and A. J. Seivers, Phys. Letters 28A, 170 (1968)

[c1] U. Kuhn and F. Luty, Solid State Commun. 2, 281 (1964) ibid.3, 31 (1965) ibid.4, 31 (1956)

[c2] I. Shepherd and G. Feher, Phys. Rev. Letters 15, 149 (1965)

[c3] U. Bosshard, R. W. Dreyfus, and W. Känzig, Phys. Kondensierten Materie 4, 254 (1965)

[c4] H. B. Shore, Phys. Rev. 151, 570 (1966)

[c5] A. F. Devonshire, Proc. Roy. Soc. (London) A153, 601 (1936)

[c6] V. Narayanamurti, Phys. Rev. Letters 13, 693 (1964)

[c7] G. Feher, I. Shepherd, and H. B. Shore, Phys. Rev. Letters 16, 500 (1966)

[c8] L. D. Shearer and T. L. Estle, Compt Rend. 14, 644 (1966) Solid State Commun. 4, 639 (1966)

[c9] W. E. Bron and R. W. Dreyfus, Phys. Rev. Letters 16, 165 (1966) Phys. Rev. 163, 304 (1967)

[c10] M. E. Baur and W. R. Salzman, Phys. Rev. 151, 710 (1966)

[c11] W. N. Lawless, Phys. Kondensierten Materie 5, 100 (1966)

[c12] C. K. Chau, M. V. Klein, and B. Wedding, Phys. Rev. Letters 17, 521 (1966)

[c13] B. Wedding, thesis, University of Illinois, 1968, (unpublished) B. Wedding and M. V. Klein, Phys. Rev. 177, 1274 (1969)

[c14] M. V. Klein, B. Wedding, and M. A. Levine, Phys. Rev. 180, 902 (1969)

[c15] M. V. Klein, Phys. Rev. 141, 489 (1966)

[c16] W. H. Flygare, W. Hüttner, R. L. Shoemaker, and P. D. Foster, J. Chem. Phys. 50, 1714 (1969)

[c17] M. V. Klein, S. O. Kennedy, T. I. Gie, and B. Wedding, Mater. Res. Bull. 3, 677 (1968)

[c18] W. H. Flygare, J. Chem. Phys. 39, 2263 (1963)

[c19] [18]

[c20] D. R. Bosomworth, Solid State Commun. 5, 681 (1967)

[c21] M. E. Baur and W. R. Salzman, Phys. Rev. Letters 18, 590 (1967)

[c22] H. S. Sack and M. C. Moriarity, Solid State Commun. 3, 93 (1965)

[c23] G. Lombardo and R. O. Pohl, Phys. Rev. Letters 15, 291 (1965)

[c24] D. Hocherl, D. Blumenstock, and H. C. Wolf, Phys. Letters 24A, 511 (1967)

[c25] G. Hocherl and H. C. Wolf, Phys. Letters 27A, 133 (1968)

[c26] M. T. Bowers, G. I. Kerley, and W. H. Flygare, J. Chem. Phys. 45, 3399 (1966)

[c27] F. Luty, J. Phys. (Paris) 28, Suppl. C-4, 120 (1967)

[c28] R. S. Scott, thesis, University of Illinois, 1968 (unpublished)

[c29] R. D. Kirby, A. E. Hughes, and A. J. Seivers, Phys. Letters 28A, 170 (1968)

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Microwave Spectroscopy of O $H^{-}$ Ions in the KCl and NaCl Lattices

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Microwave Spectroscopy of OH− Ions in the KCl and NaCl Lattices

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Microwave Spectroscopy of O $H^{-}$ Ions in the KCl and NaCl Lattices