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Nuclear Spin-Lattice Relaxation in Liquid Nontransition Metals
Phys. Rev. 178, 641 – Published 10 February, 1969
DOI: https://doi.org/10.1103/PhysRev.178.641
Abstract
We develop a broad interpretation for nuclear spin-lattice relaxation in liquid nontransition metals using our new data for and previously reported data for , , , , and . Our work provides new insight into the relative importance of the various contributions to the NMR shift and the nuclear spin-lattice relaxation rate . The three potentially significant contributions to are the hyperfine contact , hyperfine orbital , and core polarization . All other contributions to are negligible. The sum of and is small compared to even in heavy elements. The first significant contribution to is the hyperfine contact rate , expressed by the Korringa relation, with , the correction factor for electron-electron interactions, having a reasonable value of about 0.75 for all metals in our study. The second and last non-negligible contribution to is the nuclear quadrupole rate arising from the effect of ionic motion on the conduction electrons, whose magnitude decreases with an increase in temperature.
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