Mössbauer Effect in <span class="aps-inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><mrow><msub><mrow><mi mathvariant="normal">K</mi></mrow><mrow><mn>3</mn></mrow></msub></mrow></math></span>Fe<span class="aps-inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><mrow><msub><mrow><mn></mn><mo>(</mo><mi mathvariant="normal">CN</mi><mo>)</mo><mn></mn></mrow><mrow><mn>6</mn></mrow></msub></mrow></math></span>

W. T. Oosterhuis; George Lang

doi:10.1103/PhysRev.178.439

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Mössbauer Effect in $K_{3}$ Fe ${(CN)}_{6}$

W. T. Oosterhuis

George Lang

Physics Department, Carnegie-Mellon University, Pittsburgh, Pennsylvania
Nuclear Physics Division, Atomic Energy Research Establishment, Harwell, England

Nuclear Physics Division, Atomic Energy Research Establishment, Harwell, England

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Phys. Rev. 178, 439 – Published 10 February, 1969Erratum Phys. Rev. 187, 768 (1969)

DOI: https://doi.org/10.1103/PhysRev.178.439

Abstract

A Mössbauer-effect study of the low-spin compound $K_{3}$ Fe ${(CN)}_{6}$ has been carried out under a wide variety of conditions. In concentrated samples, the quadrupole splitting, linewidth, and isomer shift were measured as a function of temperature. The components of the electric-field-gradient tensor (EFG) were determined from the quadrupole peak area ratios of single-crystal absorbers at 20 and 300°K. The orientations of the $g$ tensor and EFG in the concentrated salt were also determined by experiments using large magnetic fields in single crystals at low temperatures. Paramagnetic hyperfine structure was found at low temperatures in samples of $K_{3}$ Fe ${(CN)}_{6}$ diluted in the diamagnetic $K_{3}$ Co ${(CN)}_{6}$ . The theory of hyperfine interactions as applied to this case is reviewed, and the sensitivity of the Mössbauer spectrum to the relative directions of the $g$ tensor and cubic field are discussed. Spectra are calculated using two models based on ESR and susceptibility results, and one of these is found to be in good agreement with the data.

Erratum

Mössbauer Effect in $K_{3}$ Fe ${(CN)}_{6}$

W. T. Oosterhuis and George Lang

Phys. Rev. 187, 768 (1969)

References (36)

C. C. Stephenson and J. C. Morrow, J. Am. Chem. Soc. 78, 275 (1956)
G. Shoffa, O. Ristan, and K. Ruckpaul, Zh. Experim. i Teor. Fiz. 35, 641 (1958) [English transl.: Soviet Physics.—JETP 8, 445 (1959)]
W. Kerler and W. Neuwirth, Z. Physik 167, 188 (1962)
R. M. Golding, Mol. Phys. 12, 13 (1967)
W. Oosterhuis, G. Lang, and S. Debenedetti, Phys. Letters 24, 346 (1967)
R. I. Ingalls, Phys. Rev. 133, A787 (1964)
J. M. Baker, B. Bleaney, and K. D. Bowers, Proc. Phys. Soc. (London) B69, 1205 (1956)
B. Bleaney and M. C. M. O'Brien, Proc. Phys. Soc. (London) B69, 1216 (1956)
C. Gottfried and J. G. Nagleschmidt, Z. Krist. 73, 357 (1930) V. Barkhatov and H. Zhadanov, Acta Physicochim. URSS 16, 43 (1942) Y. Okaya et al., Acta Cryst. 10, 798 (1957)
N. A. Curry and W. A. Runciman, Acta Cryst. 12, 674 (1959) J. A. Kohn and W. D. Townes, ibid. 14, 617 (1961) J. O. Artman, J. C. Murphy, J. A. Kohn, and W. D. Townes, Phys. Rev. Letters 4, 607 (1960)
D. Davis and R. J. Kurland, J. Chem. Phys. 46, 388 (1967)
T. E. Cranshaw, Nucl. Instr. Methods 30, 101 (1964)
L. Epstein (private communication)
A. V. Kiss, J. Abraham, and I. Hegedus, Z. Anorg. Allgem. Chem. 244, 98 (1940)
R. S. Preston, S. S. Hanna, and J. Herberle, Phys. Rev. 128, 2207 (1962)
L. Pauling, J. Am. Chem. Soc. 53, 1367 (1931)
W. G. Penney and R. Schlapp, Phys. Rev. 41, 194 (1932)
R. G. Shulman and S. Sugano, J. Chem. Phys. 42, 39 (1965)
J. Howard, J. Chem. Phys. 3, 813 (1935)
Omitted endnote
C. J. Ballhausen, Introduction to Ligand Field Theory (McGraw-Hill Book Co., New York, 1962), p. 154
R. M. Sternheimer, Phys. Rev. 130, 1423 (1963) G. Burns, ibid. 124, 524 (1961)
T. Sugawara, J. Phys. Soc. Japan 24, 858 (1959)
Omitted endnote
R. E. Watson and A. J. Freeman, Phys. Rev. 123, 2027 (1961) Magnetism, edited by G. Rado and H. Suhl, (Academic Press Inc., New York, 1965), Vol. 11A, p. 291
G. Lang and W. Marshall, Proc. Phys. Soc. (London) 87, 3 (1966)
J. C. M. Henning, Phys. Letters 24A, 40 (1967) J. S. Van Wieringgen, Discussions Faraday Soc. 119, 118 (1955)
C. E. Johnson, Proc. Phys. Soc. (London) 92, 748 (1967)
B. A. Scott and R. A. Bernheim, J. Chem. Phys. 44, 2004 (1965) Phys. Rev. 123, 2070 (1961)
S. De Benedetti, Nuclear Interactions (J. Wiley & Sons, Inc., New York, 1964), p. 264
P. Zory, Phys. Rev. 140, A1401 (1965)
V. I. Goldanskii, Phys. Rev. Letters 14, 769 (1965)
L. E. Campbell and S. De Benedetti, Phys. Letters 20, 102 (1966) F. E. Obenshain et al., Phys. Rev. Letters 14, 365 (1965) H. H. Wickman and A. U. Trozzolo, ibid. 15, 156 (1965) H. H. Wickman and G. K. Wertheim, Phys. Rev. 148, 211 (1966)
E. Bradford and W. Marshall, Proc. Phys. Soc. (London) 87, 731 (1966) M. Blume and A. J. Tjon, Phys. Rev. (to be published) H. H. Wickman, Mössbauer Effect Methodology (Plenum Press, Inc., New York, 1966), Vol. 2, p. 39
R. J. Anderson (private communication)
M. H. Cohen and F. Reif, Solid State Phys. 5, 321 (1957)

[c1] C. C. Stephenson and J. C. Morrow, J. Am. Chem. Soc. 78, 275 (1956)

[c2] G. Shoffa, O. Ristan, and K. Ruckpaul, Zh. Experim. i Teor. Fiz. 35, 641 (1958) [English transl.: Soviet Physics.—JETP 8, 445 (1959)]

[c3] W. Kerler and W. Neuwirth, Z. Physik 167, 188 (1962)

[c4] R. M. Golding, Mol. Phys. 12, 13 (1967)

[c5] W. Oosterhuis, G. Lang, and S. Debenedetti, Phys. Letters 24, 346 (1967)

[c6] R. I. Ingalls, Phys. Rev. 133, A787 (1964)

[c7] J. M. Baker, B. Bleaney, and K. D. Bowers, Proc. Phys. Soc. (London) B69, 1205 (1956)

[c8] B. Bleaney and M. C. M. O'Brien, Proc. Phys. Soc. (London) B69, 1216 (1956)

[c9] C. Gottfried and J. G. Nagleschmidt, Z. Krist. 73, 357 (1930) V. Barkhatov and H. Zhadanov, Acta Physicochim. URSS 16, 43 (1942) Y. Okaya et al., Acta Cryst. 10, 798 (1957)

[c10] N. A. Curry and W. A. Runciman, Acta Cryst. 12, 674 (1959) J. A. Kohn and W. D. Townes, ibid. 14, 617 (1961) J. O. Artman, J. C. Murphy, J. A. Kohn, and W. D. Townes, Phys. Rev. Letters 4, 607 (1960)

[c11] D. Davis and R. J. Kurland, J. Chem. Phys. 46, 388 (1967)

[c12] T. E. Cranshaw, Nucl. Instr. Methods 30, 101 (1964)

[c13] L. Epstein (private communication)

[c14] A. V. Kiss, J. Abraham, and I. Hegedus, Z. Anorg. Allgem. Chem. 244, 98 (1940)

[c15] R. S. Preston, S. S. Hanna, and J. Herberle, Phys. Rev. 128, 2207 (1962)

[c16] L. Pauling, J. Am. Chem. Soc. 53, 1367 (1931)

[c17] W. G. Penney and R. Schlapp, Phys. Rev. 41, 194 (1932)

[c18] R. G. Shulman and S. Sugano, J. Chem. Phys. 42, 39 (1965)

[c19] J. Howard, J. Chem. Phys. 3, 813 (1935)

[c20] Omitted endnote

[c21] C. J. Ballhausen, Introduction to Ligand Field Theory (McGraw-Hill Book Co., New York, 1962), p. 154

[c22] R. M. Sternheimer, Phys. Rev. 130, 1423 (1963) G. Burns, ibid. 124, 524 (1961)

[c23] T. Sugawara, J. Phys. Soc. Japan 24, 858 (1959)

[c24] Omitted endnote

[c25] R. E. Watson and A. J. Freeman, Phys. Rev. 123, 2027 (1961) Magnetism, edited by G. Rado and H. Suhl, (Academic Press Inc., New York, 1965), Vol. 11A, p. 291

[c26] G. Lang and W. Marshall, Proc. Phys. Soc. (London) 87, 3 (1966)

[c27] J. C. M. Henning, Phys. Letters 24A, 40 (1967) J. S. Van Wieringgen, Discussions Faraday Soc. 119, 118 (1955)

[c28] C. E. Johnson, Proc. Phys. Soc. (London) 92, 748 (1967)

[c29] B. A. Scott and R. A. Bernheim, J. Chem. Phys. 44, 2004 (1965) Phys. Rev. 123, 2070 (1961)

[c30] S. De Benedetti, Nuclear Interactions (J. Wiley & Sons, Inc., New York, 1964), p. 264

[c31] P. Zory, Phys. Rev. 140, A1401 (1965)

[c32] V. I. Goldanskii, Phys. Rev. Letters 14, 769 (1965)

[c33] L. E. Campbell and S. De Benedetti, Phys. Letters 20, 102 (1966) F. E. Obenshain et al., Phys. Rev. Letters 14, 365 (1965) H. H. Wickman and A. U. Trozzolo, ibid. 15, 156 (1965) H. H. Wickman and G. K. Wertheim, Phys. Rev. 148, 211 (1966)

[c34] E. Bradford and W. Marshall, Proc. Phys. Soc. (London) 87, 731 (1966) M. Blume and A. J. Tjon, Phys. Rev. (to be published) H. H. Wickman, Mössbauer Effect Methodology (Plenum Press, Inc., New York, 1966), Vol. 2, p. 39

[c35] R. J. Anderson (private communication)

[c36] M. H. Cohen and F. Reif, Solid State Phys. 5, 321 (1957)

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Mössbauer Effect in $K_{3}$ Fe ${(CN)}_{6}$

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Mössbauer Effect in $K_{3}$ Fe ${(CN)}_{6}$

References (36)

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Mössbauer Effect in K3Fe(CN)6

Abstract

Erratum

Mössbauer Effect in K3Fe(CN)6

References (36)

Mössbauer Effect in $K_{3}$ Fe ${(CN)}_{6}$

Mössbauer Effect in $K_{3}$ Fe ${(CN)}_{6}$