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J. P. Van Der Ziel; H. J. Guggenheim

doi:10.1103/PhysRev.166.479

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Optical Spectrum of Co $F_{2}$

J. P. Van Der Ziel and H. J. Guggenheim

Bell Telephone Laboratories, Murray Hill, New Jersey

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Phys. Rev. 166, 479 – Published 10 February, 1968

DOI: https://doi.org/10.1103/PhysRev.166.479

Abstract

The polarized absorption of Co $F_{2}$ has been studied from 0.4 to 2.0 μ. The spectrum consists of sharp magnetic-dipole lines followed on the high-energy side by structure with electric-dipole polarization. The ${}^{4}{Γ_{5}}^{+}$ spin-allowed transition in the infrared is found to have magnetic-dipole-polarized magnon sidebands. The spin-forbidden transitions have magnon sidebands with electric-dipole polarization. Sidebands resulting from the simultaneous absorption of optical and low-energy excitons are also observed. The magnetic-field and temperature dependence of the absorption lines are reported.

References (31)

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[c1] R. L. Greene, D. D. Sell, W. M. Yen, A. L. Schawlow, and R. M. White, Phys. Rev. Letters 15, 656 (1965)

[c2] D. D. Sell, R. L. Greene, W. M. Yen, A. L. Schawlow, and R. M. White, J. Appl. Phys. 37, 1229 (1966)

[c3] R. E. Dietz, A. Misetich, and H. J. Guggenheim, Phys. Rev. Letters 16, 841 (1966)

[c4] Y. Tanabe and K. Gondaira, J. Phys. Soc. Japan 22, 573 (1967)

[c5] P. G. Russell, D. S. McClure, and J. W. Stout, Phys. Rev. Letters 16, 176 (1966)

[c6] V. V. Eremenko and A. I. Belyaeva, Fiz. Tverd. Tela 6, 3646 (1964) [English transl.: Soviet Phys.—Solid State 6, 2918 (1965)]

[c7] J. O. Dimmock and R. G. Wheeler, Phys. Rev. 127, 391 (1962)

[c8] P. L. Richards, J. Appl. Phys. 35, 850 (1964)

[c9] R. Loudon (to be published)

[c10] A. S. Davydov, Theory of Molecular Excitons (McGraw-Hill Book Co., Inc., New York, 1962)

[c11] R. S. Knox, Solid State Phys. Suppl. 5, 1 (1963)

[c12] D. L. Dexter and R. W. Heller, Phys. Rev. 91, 273 (1953) D. L. Dexter, ibid. 126, 1962 (1962)

[c13] L. N. Ovander, Fiz. Tverd. Tela 4, 294 (1962) [English transl.: Soviet Phys.—Solid State 4, 212 (1962)]

[c14] M. Lax and J. J. Hopfield, Phys. Rev. 124, 115 (1961)

[c15] J. Tylicki, F. L. Scarpace, M. W. Passow, and W. M. Yen, Bull. Am. Phys. Soc. 12, 285 (1967)

[c16] P. S. Narayanan, Proc. Indian Acad. Sci. 32A, 279 (1950)

[c17] A. S. Barker, Jr. and J. A. Ditzenberger, Solid State Commun. 3, 131 (1965)

[c18] S. P. S. Porto, P. A. Fleury, and T. C. Damen, Phys. Rev. 154, 522 (1967)

[c19] W. Low, Phys. Rev. 109, 256 (1958)

[c20] H. M. Gladney, Phys. Rev. 146, 253 (1966)

[c21] H. Kamimura and Y. Tanabe, J. Appl. Phys. 34, 1239 (1963)

[c22] M. E. Lines, Phys. Rev. 137, A982 (1965)

[c23] L. F. Johnson, R. E. Dietz, and H. J. Guggenheim, Appl. Phys. Letters 5, 21 (1964)

[c24] R. Newman and R. M. Chrenko, Phys. Rev. 115, 1147 (1959)

[c25] R. A. Cowley, P. Martel, and R. W. H. Stevenson, Phys. Rev. Letters 18, 162 (1967)

[c26] H. J. Guggenheim, J. Appl. Phys. 34, 2482 (1963)

[c27] A. Abragam and M. H. L. Pryce, Proc. Roy. Soc. (London) A206, 175 (1951)

[c28] W. M. Yen (private communication)

[c29] J. P. van der Ziel, Phys. Rev. Letters 18, 237 (1967) Phys. Rev. 161, 483 (1967)

[c30] J. Ferguson, D. L. Wood, and K. Knox, J. Chem. Phys. 39, 881 (1963)

[c31] S. J. Allen, Jr. (unpublished)

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Optical Spectrum of Co $F_{2}$

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Optical Spectrum of CoF2

Abstract

References (31)

Optical Spectrum of Co $F_{2}$