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  • Access by Xinjiang University

Millimeter- and Submillimeter-Wave Spectra and Molecular Constants of Silver Chloride

Edwin Pearson and Walter Gordy

  • Department of Physics, Duke University, Durham, North Carolina

Phys. Rev. 152, 42 – Published 2 December, 1966

DOI: https://doi.org/10.1103/PhysRev.152.42

Abstract

A new type of high-temperature spectrometer for operation in the millimeter- and submillimeter-wave regions has been constructed and used for measurements of numerous rotational transitions of AgCl at 750°C. Significant improvement in sensitivity over other high-temperature spectrometers operating in the submillimeter region has been achieved. With it, rotational lines of AgCl up to a frequency of 366 858.51 Mc/sec (λ=0.8 mm) have been measured with high precision. The molecular constants obtained are. For Ag107Cl35, Be=3686.9639 Mc/sec, αe=17.8498 Mc/sec, γe=0.01883 Mc/sec, De=1.8903 kc/sec, ωe=343.52 cm1, ωexe=1.169 cm1, re=2.28078 Å; for Ag109Cl35, Be=3670.2777 Mc/sec, αe=17.7284 Mc/sec, γe=0.01859 Mc/sec, De=1.8739 kc/sec, ωe=342.68 cm1, ωexe=1.163 cm1, re=2.280779 Å; for Ag107Cl37, Be=3536.8734, αe=16.7705 Mc/sec, γe=0.01708 Mc/sec, De=1.7383 kc/sec, ωe=336.58 cm1, ωexe=1.118 cm1, re=2.280781 Å; for Ag109Cl37, Be=3520.1846 Mc/sec, αe=16.6520 Mc/sec, γe=0.01710 Mc/sec, De=1.7192 kc/sec, ωe=336.04 cm1, ωexe=1.121 cm1, re=2.280782.

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