Nuclear Magnetic Resonance in the Paramagnetic States of MnO, <span class="aps-inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><mi>α</mi><mo>−</mo><mi mathvariant="normal">M</mi><mi mathvariant="normal">n</mi><mi mathvariant="normal">S</mi></math></span>, and <span class="aps-inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><mi>α</mi><mo>−</mo><mi mathvariant="normal">M</mi><mi mathvariant="normal">n</mi><mi mathvariant="normal">S</mi><mi mathvariant="normal">e</mi></math></span>

E. D. Jones

doi:10.1103/PhysRev.151.315

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Nuclear Magnetic Resonance in the Paramagnetic States of MnO, $α - M n S$ , and $α - M n S e$

E. D. Jones

Sandia Laboratory, Albuquerque, New Mexico

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Phys. Rev. 151, 315 – Published 4 November, 1966Erratum Phys. Rev. 155, 566 (1967)

DOI: https://doi.org/10.1103/PhysRev.151.315

Abstract

The ${Mn}^{55}$ and ${Se}^{77}$ NMR have been observed in the paramagnetic states of the antiferromagnetic compounds MnO, $α - M n S$ , and $α - M n S e$ . The ${Mn}^{55}$ and ${Se}^{77}$ NMR frequency shifts were found to be temperature-dependent and proportional to the magnetic susceptibility. From an analysis of the NMR frequency shift and magnetic-susceptibility data, the following hyperfine coupling constants were determined: $A^{55} (MnO) = - (81.5 \pm 2.5) \times 10^{- 4}$ ${cm}^{- 1}$ , $A^{55} (α - M n S) = - (71.8 \pm 5.3) \times 10^{- 4}$ ${cm}^{- 1}$ , $A^{55} (α - M n S e) = - (67.0 \pm 4.5) \times 10^{- 4}$ ${cm}^{- 1}$ and $A^{77} (α - M n S e) = + (7.2 \pm 0.6) \times 10^{- 4}$ ${cm}^{- 1}$ . Additional information regarding the Néel temperatures of $α - M n S$ and $α - M n S e$ was obtained by studying the temperature dependence of the ${Mn}^{55}$ NMR intensity with the result $T_{N} (α - M n S) = (147 \pm 1)$ °K and $T_{N} (α - M n S e) ≃ 150$ °K. The experimental ${Mn}^{55}$ and ${Se}^{77}$ NMR linewidths were found to be in agreement with predictions based upon the theory of exchange-narrowed hyperfine-broadened NMR linewidths in paramagnetic insulators.

Erratum

Nuclear Magnetic Resonance in the Paramagnetic States of MnO, $α - M n S$ , and $α - M n S e$

E. D. Jones

Phys. Rev. 155, 566 (1967)

References (36)

T. Moriya, Progr. Theoret. Phys. (Kyoto) 16, 641 (1956)
V. Jaccarino and A. Portis, in Magnetism, edited by H. Suhl and G. Rado (Academic Press Inc., New York, 1965), Vol. IIA
R. G. Shulman, Phys. Rev. Letters 2, 459 (1959)
E. D. Jones, J. Appl. Phys. 36, 919 (1965)
E. D. Jones, Phys. Letters 18, 98 (1965)
J. J. Banewicz, R. F. Heidelberg, and A. H. Luxem, J. Phys. Chem. 65, 615 (1961)
J. A. Poulis, C. H. Massen, and P. Van der Leeden, J. Phys. Soc. Japan 17, Suppl. B-1, 212 (1962)
H. Bizette, B. Squire, and B. Tsai, Compt. Rend. 207, 449 (1938)
W. D. Johnston and R. R. Heikes, J. Am. Chem. Soc. 78, 3255 (1956)
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S. S. Bhatnager, A. Cameron, E. H. Harbard, P. L. Kapur, A. King, and B. Prakash, J. Chem. Soc. 11, 1433 (1939)
H. Bizette and B. Tsai, Compt. Rend. 217, 444 (1943)
R. W. Tyler, Phys. Rev. 44, 776 (1933)
R. W. Millar, J. Am. Chem. Soc. 50, 1875 (1928)
S. S. Todd and K. R. Bonnickson, J. Am. Chem. Soc. 73 3894 (1951)
D. E. O'Reilly and T. Tsang, J. Chem. Phys. 40, 734 (1964)
W. M. Walsh, Jr. (private communication)
L. R. Maxwell and T. R. McGuire, Rev. Mod. Phys. 25, 279 (1953)
V. Jaccarino (unpublished data)
J. J. Banewicz and R. Lindsay, Phys. Rev. 104, 318 (1956)
R. Lindsay and J. J. Banewicz, Phys. Rev. 110, 634 (1958)
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C. T. Anderson, J. Am. Chem. Soc. 53, 476 (1931)
R. Lindsay (private communication)
A. Danielian, Proc. Phys. Soc. (London) 80, 981 (1962)
M. E. Lines and E. D. Jones, Phys. Rev. 139, A1313 (1965)
H. Bizette and B. Tsai, Compt. Rend. 212, 75 (1941)
A. Serres, J. Phys. Radium 8, 146 (1947)
R. Lindsay, Phys. Rev. 84, 569 (1951)
A. Taylor, Appl. Sectry. 14, 116 (1960)
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[c1] T. Moriya, Progr. Theoret. Phys. (Kyoto) 16, 641 (1956)

[c2] V. Jaccarino and A. Portis, in Magnetism, edited by H. Suhl and G. Rado (Academic Press Inc., New York, 1965), Vol. IIA

[c3] R. G. Shulman, Phys. Rev. Letters 2, 459 (1959)

[c4] E. D. Jones, J. Appl. Phys. 36, 919 (1965)

[c5] E. D. Jones, Phys. Letters 18, 98 (1965)

[c6] J. J. Banewicz, R. F. Heidelberg, and A. H. Luxem, J. Phys. Chem. 65, 615 (1961)

[c7] J. A. Poulis, C. H. Massen, and P. Van der Leeden, J. Phys. Soc. Japan 17, Suppl. B-1, 212 (1962)

[c8] H. Bizette, B. Squire, and B. Tsai, Compt. Rend. 207, 449 (1938)

[c9] W. D. Johnston and R. R. Heikes, J. Am. Chem. Soc. 78, 3255 (1956)

[c10] T. R. McGuire and R. J. Happel, Jr., J. Phys. Radium 20, 424 (1959)

[c11] S. S. Bhatnager, A. Cameron, E. H. Harbard, P. L. Kapur, A. King, and B. Prakash, J. Chem. Soc. 11, 1433 (1939)

[c12] H. Bizette and B. Tsai, Compt. Rend. 217, 444 (1943)

[c13] R. W. Tyler, Phys. Rev. 44, 776 (1933)

[c14] R. W. Millar, J. Am. Chem. Soc. 50, 1875 (1928)

[c15] S. S. Todd and K. R. Bonnickson, J. Am. Chem. Soc. 73 3894 (1951)

[c16] D. E. O'Reilly and T. Tsang, J. Chem. Phys. 40, 734 (1964)

[c17] W. M. Walsh, Jr. (private communication)

[c18] L. R. Maxwell and T. R. McGuire, Rev. Mod. Phys. 25, 279 (1953)

[c19] V. Jaccarino (unpublished data)

[c20] J. J. Banewicz and R. Lindsay, Phys. Rev. 104, 318 (1956)

[c21] R. Lindsay and J. J. Banewicz, Phys. Rev. 110, 634 (1958)

[c22] J. J. Banewicz, R. F. Heidelberg, and R. Lindsay, Phys. Rev. 117, 736 (1960)

[c23] C. T. Anderson, J. Am. Chem. Soc. 53, 476 (1931)

[c24] R. Lindsay (private communication)

[c25] A. Danielian, Proc. Phys. Soc. (London) 80, 981 (1962)

[c26] M. E. Lines and E. D. Jones, Phys. Rev. 139, A1313 (1965)

[c27] H. Bizette and B. Tsai, Compt. Rend. 212, 75 (1941)

[c28] A. Serres, J. Phys. Radium 8, 146 (1947)

[c29] R. Lindsay, Phys. Rev. 84, 569 (1951)

[c30] A. Taylor, Appl. Sectry. 14, 116 (1960)

[c31] O. Matamura, J. Phys. Soc. Japan 14, 108 (1959)

[c32] B. R. McGarvey and H. S. Gutowsky, J. Chem. Phys. 20, 1472 (1952)

[c33] P. W. Anderson and P. R. Weiss, Rev. Mod. Phys. 25, 269 (1953)

[c34] P. W. Anderson, J. Phys. Soc. Japan 9, 316 (1954)

[c35] R. Kubo and K. Tomita, J. Phys. Soc. Japan 9, 888 (1954)

[c36] M. E. Lines and E. D. Jones, Phys. Rev. 141, 525 (1966)

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Nuclear Magnetic Resonance in the Paramagnetic States of MnO, $α - M n S$ , and $α - M n S e$

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Erratum

Nuclear Magnetic Resonance in the Paramagnetic States of MnO, $α - M n S$ , and $α - M n S e$

References (36)

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Nuclear Magnetic Resonance in the Paramagnetic States of MnO, α−MnS, and α−MnSe

Abstract

Erratum

Nuclear Magnetic Resonance in the Paramagnetic States of MnO, α−MnS, and α−MnSe

References (36)

Nuclear Magnetic Resonance in the Paramagnetic States of MnO, $α - M n S$ , and $α - M n S e$

Nuclear Magnetic Resonance in the Paramagnetic States of MnO, $α - M n S$ , and $α - M n S e$