Electric Quadrupole Effects in Nuclear Magnetic Resonance in the Case of Large Nuclear Spin. The Nuclear-Magnetic-Resonance Spectrum of Solid Indium

R. G. Barnes; D. J. Genin; R. G. Lecander; D. R. Torgeson

doi:10.1103/PhysRev.145.302

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Electric Quadrupole Effects in Nuclear Magnetic Resonance in the Case of Large Nuclear Spin. The Nuclear-Magnetic-Resonance Spectrum of Solid Indium

R. G. Barnes, D. J. Genin, R. G. Lecander, and D. R. Torgeson

Institute for Atomic Research and Department of Physics, Iowa State University, Ames, Iowa

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Phys. Rev. 145, 302 – Published 6 May, 1966

DOI: https://doi.org/10.1103/PhysRev.145.302

Abstract

The nuclear-magnetic-resonance spectrum of ${In}^{115}$ in polycrystalline indium (powder) reveals a number of unusual features stemming from the combination of large quadrupole interaction and large nuclear spin ( $I = \frac{9}{2}$ ). The crossing of several Zeeman transitions, the occurrence of non-90° satellite lines, and the occurrence of forbidden transitions ( $Δ m = \pm 2$ ) have been verified experimentally, and the experimental results have been compared with a detailed theoretical calculation of the spectrum based on exact numerical diagonalization of the secular determinant. At room temperature, the isotropic and anisotropic Knight-shift tensor components have the values $K_{iso} = + (0.82 \pm 0.04) %$ and $K_{ax} = - (0.14 \pm 0.04) %$ .

References (17)

D. R. Torgeson and R. G. Barnes, Phys. Rev. Letters 9, 255 (1962)
R. G. Barnes, F. Borsa, S. L. Segel, and D. R. Torgeson, Phys. Rev. 137, A1828 (1965)
T. J. Rowland, in Progress in Material Science, edited by Bruce Chalmers (Pergamon Press, Inc., New York, 1961), Vol. 9
W. H. Jones, Jr., and F. J. Milford, Phys. Rev. 125, 1259 (1962)
R. R. Hewitt and B. F. Williams, Phys. Rev. Letters 12, 216 (1964)
G. M. Volkoff, Can. J. Phys. 31, 820 (1953)
W. H. Jones, Jr., T. P. Graham, and R. G. Barnes, Phys. Rev. 132, 1898 (1963)
M. H. Cohen and F. Reif, in Solid State Physics, edited by F. Seitz and D. Turnbull (Academic Press Inc., New York, 1957), Vol. 5, p. 321
W. W. Simmons and C. P. Slichter, Phys. Rev. 121, 1580 (1961)
F. Borsa and R. G. Barnes, J. Phys. Chem. Solids 25, 1305 (1964)
D. G. Hughes and T. J. Rowland, Can. J. Phys. 42, 209 (1964)
R. R. Hewitt and T. T. Taylor, Phys. Rev. 125, 524 (1962)
K. Kambe and J. F. Ollom, J. Phys. Soc. Japan 11, 50 (1956)
W. Knight, Phys. Rev. 104, 271 (1956)
D. R. Torgeson and R. G. Barnes, Phys. Rev. 136, A738 (1964)
B. R. McCart and R. G. Barnes (to be published)
R. R. Hewitt, J. E. Adams, Jr., and L. Berry, Bull. Am. Phys. Soc. 9, 732 (1964)

[c1] D. R. Torgeson and R. G. Barnes, Phys. Rev. Letters 9, 255 (1962)

[c2] R. G. Barnes, F. Borsa, S. L. Segel, and D. R. Torgeson, Phys. Rev. 137, A1828 (1965)

[c3] T. J. Rowland, in Progress in Material Science, edited by Bruce Chalmers (Pergamon Press, Inc., New York, 1961), Vol. 9

[c4] W. H. Jones, Jr., and F. J. Milford, Phys. Rev. 125, 1259 (1962)

[c5] R. R. Hewitt and B. F. Williams, Phys. Rev. Letters 12, 216 (1964)

[c6] G. M. Volkoff, Can. J. Phys. 31, 820 (1953)

[c7] W. H. Jones, Jr., T. P. Graham, and R. G. Barnes, Phys. Rev. 132, 1898 (1963)

[c8] M. H. Cohen and F. Reif, in Solid State Physics, edited by F. Seitz and D. Turnbull (Academic Press Inc., New York, 1957), Vol. 5, p. 321

[c9] W. W. Simmons and C. P. Slichter, Phys. Rev. 121, 1580 (1961)

[c10] F. Borsa and R. G. Barnes, J. Phys. Chem. Solids 25, 1305 (1964)

[c11] D. G. Hughes and T. J. Rowland, Can. J. Phys. 42, 209 (1964)

[c12] R. R. Hewitt and T. T. Taylor, Phys. Rev. 125, 524 (1962)

[c13] K. Kambe and J. F. Ollom, J. Phys. Soc. Japan 11, 50 (1956)

[c14] W. Knight, Phys. Rev. 104, 271 (1956)

[c15] D. R. Torgeson and R. G. Barnes, Phys. Rev. 136, A738 (1964)

[c16] B. R. McCart and R. G. Barnes (to be published)

[c17] R. R. Hewitt, J. E. Adams, Jr., and L. Berry, Bull. Am. Phys. Soc. 9, 732 (1964)

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Electric Quadrupole Effects in Nuclear Magnetic Resonance in the Case of Large Nuclear Spin. The Nuclear-Magnetic-Resonance Spectrum of Solid Indium

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