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Sum Rules for Hydrogenic Wave Functions, with Applications to Charge-Exchange and Ionization Processes
Phys. Rev. 136, A669 – Published 2 November, 1964
DOI: https://doi.org/10.1103/PhysRev.136.A669
Abstract
We prove some general addition theorems for certain matrix elements which involve hydrogen-atom wave functions. In particular, if is the Fourier transform of the hydrogen-atom wave function with quantum numbers , , , then summed over all and for a given is equal to , where is the Bohr radius. Two applications of the theorems are given. Firstly, we consider charge-exchange reactions of the type and use our general theorems to obtain for the cross section for reactions proceeding from the initial atomic state to the final state an expression which is both simple and fully exact (in Born approximation). Secondly, we indicate how the theorems may be applied to get simple expressions for the cross sections for ionization of excited hydrogen atoms by various processes.
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