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  • Access by Xinjiang University

Sum Rules for Hydrogenic Wave Functions, with Applications to Charge-Exchange and Ionization Processes

Robert M. May

  • The Daily Telegraph Theoretical Department, School of Physics, University of Sydney, Sydney, Australia

Phys. Rev. 136, A669 – Published 2 November, 1964

DOI: https://doi.org/10.1103/PhysRev.136.A669

Abstract

We prove some general addition theorems for certain matrix elements which involve hydrogen-atom wave functions. In particular, if fnlm(q) is the Fourier transform of the hydrogen-atom wave function with quantum numbers n, l, m, then |fnlm(q)|2 summed over all l and m for a given n is equal to 2π6a05n3×(q2+a02n2)4, where a0 is the Bohr radius. Two applications of the theorems are given. Firstly, we consider charge-exchange reactions of the type H++H(n1l1m1)H(n2l2m2)+H+ and use our general theorems to obtain for the cross section for reactions proceeding from the initial atomic state n1 to the final state n2 an expression which is both simple and fully exact (in Born approximation). Secondly, we indicate how the theorems may be applied to get simple expressions for the cross sections for ionization of excited hydrogen atoms by various processes.

References (14)

  1. R. Courant and D. Hilbert, Methods of Mathematical Physics (Interscience Publishers, Inc., New York, 1953), Vol. I, p. 95
  2. Omitted endnote

  3. D. R. Bates and A. Dalgarno, Proc. Phys. Soc. (London) A66, 972 (1953)
  4. J. R. Oppenheimer, Phys. Rev. 31, 349 (1928)
  5. S. T. Butler, R. M. May, and I. D. S. Johnston, Phys. Letters (to be published)
  6. S. T. Butler and I. D. S. Johnston, Nucl. Fusion (to be published)
  7. R. M. May, Nucl. Fusion (to be published)
  8. J. R. Hiskes and M. H. Mittleman, U. S. Atomic Energy Commission Report UCRL-9969 1962, p. 128 (unpublished)
  9. H. A. Bethe and E. E. Salpeter, Quantum Mechanics of One- and Two-Electron Atoms (Academic Press Inc., New York, 1957), p. 39
  10. P. M. Morse and H. Feshbach, Methods of Theoretical Physics (McGraw-Hill Book Company, Inc., New York, 1953), Vol. I, p. 784
  11. [3,4] [6] J. A. Gaunt [Proc. Cambridge Phil. Soc. 23, 732 (1927)] J. W. Frame [ 27, 511 (1931)] T-Y. Wu and T. Ohmura, Quantum Theory of Scattering (Prentice-Hall, Inc., Englewood Cliffs, New Jersey, 1962), Sec. M
  12. M. Gell-Mann and M. L. Goldberger, Phys. Rev. 91, 398 (1953)
  13. L. I. Schiff, Quantum Mechanics (McGraw-Hill Book Company, Inc., New York, 1955), p. 273
  14. Wu and Ohmura [11], p. 225

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