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Electrostatically Correlated Spin-Orbit Interactions in -Type Configurations
Phys. Rev. 134, A596 – Published 4 May, 1964
DOI: https://doi.org/10.1103/PhysRev.134.A596
Abstract
It is shown that, in second-order perturbation theory, electrostatically correlated spin-orbit interactions give rise to a "screening" of the spin-orbit coupling constant of an -type configuration. In addition to this "screening" effect, these interactions also lead to an effective spin-other-orbit interaction which is not included in the usual empirical least-squares determination of the Coulomb and spin-orbit parameters. The consequences of this overt effect are discussed.
References (6)
- K. Rajnak and B. G. Wybourne, Phys. Rev. 132, 280 (1963)
- B. G. Wybourne, J. Chem. Phys. 36, 2301 (1962)
- H. Lammermann and J. G. Conway, J. Chem. Phys. 38, 259 (1963)
- E. U. Condon and G. H. Shortley, Theory of Atomic Spectra (Cambridge University Press, New York, 1935)
- H. Horie, Progr. Theoret. Phys. (Kyoto) 10, 296 (1953)
- G. Racah, Phys. Rev. 63, 367 (1943)