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Level Crossing Determination of τ(P11) and gJ(P13 in Zinc and the hfs of Zn65 and Zn67

A. Landman* and R. Novick

  • Columbia Radiation Laboratory, Columbia University, New York, New York

  • *Present address: Institute for the Study of Metals, University of Chicago, Chicago, Illinois.
  • Alfred P. Sloan Foundation Fellow.

Phys. Rev. 134, A56 – Published 6 April, 1964

DOI: https://doi.org/10.1103/PhysRev.134.A56

Abstract

Optical detection of level crossing in the (4s4p)P13 state of stable Zn67 and of 245-day Zn65, using the intercombination line at 3076 Å, has resulted in a precise determination of the ratios of the dipole and quadrupole hyperfine coupling constants in each of the isotopes to the Landé gJ factor of this state. Using these results and the values of the dipole coupling constant for each isotope, as determined from double resonance experiments, we obtain the following values for the atomic g factor and "isolated" quadrupole interaction constants: Zn67: gJ=1.501006(8) and B=18.770(12) Mc/sec, Zn65: gJ=1.500984(20) and B=2.867(12) Mc/sec. The results for B agree with those obtained from double resonance, indicating the adequacy of our treatment of the second-order fine-structure corrections. The lifetime (τ) of the (4s4p)P11 state of Zn has been determined to be τ=(1.38±0.05)×109 sec through the observation of the zero-field level crossing (Hanle effect), using the resonance line at 2138 Å. These latter experiments were performed with natural zinc (96% even isotopes), and included the quantitative determination of coherence narrowing.

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